Organic electroluminescence device and electronic apparatus provided with the same

ABSTRACT

An organic electroluminescence device including a cathode, an anode, and an emitting layer disposed between the cathode and the anode, wherein the emitting layer includes a compound represented by the following formula (1) and one or more compounds selected from the group consisting of compounds represented by formulas (11), (21), (31), (41), (51), (61), (71) and (81). In the formula (1), at least one of R 1  to R 8  is a deuterium atom, and Ar 2  is a monovalent group represented by following formula (2), (3) or (4).

CROSS-REFERENCE TO RELATED APPLICATIONS

The present application claims priority to and the benefit of JapanesePatent Application Nos. 2018-191297, filed on Oct. 9, 2018, and2019-101674, filed on May 30, 2019. The contents of these applicationsare hereby incorporated by reference in their entireties.

TECHNICAL FIELD

The invention relates to an organic electroluminescence device and anelectronic apparatus provided with the organic electroluminescencedevice.

BACKGROUND ART

When a voltage is applied to an organic electroluminescence device(hereinafter may be referred to as an organic EL device), holes areinjected to an emitting layer from an anode and electrons are injectedto an emitting layer from a cathode. In the emitting layer, injectedholes and electrons are re-combined and excitons are formed.

Although materials for an organic EL device are being improved graduallyto increase the performances of the organic EL device (for example,Patent Documents 1 to 3), high performances are further offered. Inparticular, improvement in lifetime of an organic EL device is animportant task relating to a lifetime of commercial products providedwith the organic EL device, and thus a material enabling to realize along-lifetime organic EL device is required.

RELATED ART DOCUMENTS Patent Documents

Patent Document 1: WO2016/152544

Patent Document 2: WO2017/188111

Patent Document 3: Publication of US Patent Application No. 2017/324045

SUMMARY OF THE INVENTION

An object of the invention is to provide an organic EL device having along lifetime, and to provide an electronic apparatus provided with theorganic EL device.

As a result of extensive studies, the inventors have found that anorganic EL device having a long lifetime can be obtained by usingcompounds having a specific structure in an emitting layer of theorganic EL device in combination, and they have achieved the invention.

According to the invention, the following organic EL device and electricapparatus can be provided.

-   1. An organic electroluminescence device comprising:

a cathode,

an anode, and

an emitting layer disposed between the cathode and the anode, wherein

the emitting layer comprises a compound represented by the followingformula (1) and one or more compounds selected from the group consistingof compounds represented by formulas (11), (21), (31), (41), (51), (61),(71) and (81):

wherein in the formula (1),

R₁ to R₈ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄).-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ maybe the same with or different from each other;

at least one of R₁ to R₈ is a deuterium atom;

two or more adjacent groups of R₁ to R₄ and two or more adjacent groupsof R₅ to R₈ do not form a ring;

L₁ and L₂ are independently

-   a single bond,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms;

Ar₁ is

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

Ar₂ is a monovalent group represented by the following formula (2), (3)or (4);

wherein in the formulas (2) to (4),

one or more pairs of two adjacent groups of R₁₅ to R₂₀ are bonded witheach other to form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

when one or more pairs of two adjacent groups of R₁₅ to R₂₀ are notbonded with each other and do not form a substituted or unsubstituted,saturated or unsaturated ring, one of R₁₁ to R₂₀ is a single bondbonding to L₂;

when one or more pairs of two adjacent groups of R₁₅ to R₂₀ are bondedwith each other to form a substituted or unsubstituted, saturated orunsaturated ring, one of R₁₅ to R₂₀ which does not form a substituted orunsubstituted, saturated or unsaturated ring and R₁₁ to R₁₄ is a singlebond bonding to L₂;

R₁₁ to R₂₀ that do not form the substituted or unsubstituted, saturatedor unsaturated ring and that are not a single bond bonding to L₂ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₃₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (11),

one or more pairs of two or more adjacent groups of R₁₀₁ to R₁₁₀ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring:

at least one of R₁₀₁ to R₁₁₀ is a monovalent group represented by theformula (12);

R₁₀₁ to R₁₁₀ that do not form the substituted or unsubstituted,saturated or unsaturated ring and that are not a monovalent grouprepresented by the following formula (12) are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (12), Ar₁₀₁ and Ar₁₀₂ are independently

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

L₁₀₁ to L₁₀₃ are independently

-   a single bonded,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms;

-   wherein, in the formula (21),

Zs are independently CR_(a) or N;

A1 ring and A₂ ring are independently a substituted or unsubstitutedaromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or asubstituted or unsubstituted heterocyclic ring having 5 to 50 ringatoms;

when plural R_(a)sexist, one or more pairs of two or more adjacentgroups of R_(a) are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

when plural R_(b)sexist, one or more pairs of two or more adjacentgroups of R_(b) are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

when plural R_(c)s exist, one or more pairs of two or more adjacentgroups of R_(c) are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

n21 and n22 are independently an integer of 0 to 4;

R_(a) to R_(c) that do not form the substituted or unsubstituted,saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₆),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;-   R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (31),

one or more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ andR₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstitutedsaturated or unsaturated ring;

R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ that do not form the substituted orunsubstituted, saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₃₂₁ and R₃₂₂ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₃₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (41),

a ring, b ring and c ring are independently

-   a substituted or unsubstituted aromatic hydrocarbon ring having 6 to    50 ring carbon atoms, or-   a substituted or unsubstituted heterocyclic ring having 5 to 50 ring    atoms;

R₄₀₁ and R₄₀₂ are independently bonded to the a ring, the b ring or thec ring to form a substituted or unsubstituted heterocyclic ring or donot form a substituted or unsubstituted heterocyclic ring;

R₄₀₁ and R₄₀₂ that do not form the substituted or unsubstitutedheterocyclic ring are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

wherein, in the formula (51),

r ring is a ring represented by the formula (52) or formula (53) whichis fused to an adjacent ring at an arbitrary position;

q ring and s ring are independently a ring represented by the formula(54) which is fused to an adjacent ring at an arbitrary position;

p ring and t ring are independently a ring represented by the formula(55) or the formula (56) which is fused to an adjacent ring at anarbitrary position;

when plural R₅₀₁s exist, adjacent plural R₅₀₁s are bonded with eachother to form a substituted or unsubstituted, saturated or unsaturatedring, or do not form a substituted or unsubstituted, saturated orunsaturated ring;

X₅₀₁ is an oxygen atom, a sulfur atom, or NR₅₀₂; p R₅₀₁ and R₅₀₂ that donot form the substituted or unsubstituted saturated or unsaturated ringare

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₆), p0 —N(R₀₀₆)(R₀₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

Ar₅₀₁ and Ar₅₀₂ are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

L₅₀₁ is

-   a substituted or unsubstituted alkylene group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenylene group having 2 to 50    carbon atoms,-   a substituted or unsubstituted alkynylene group having 2 to 50    carbon atoms,-   a substituted or unsubstituted cycloalkylene group having 3 to 50    ring carbon atoms,-   a substituted or unsubstituted arylene group having 6 to 50 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 50 ring atoms;

m1 is an integer of 0 to 2, m2 is an integer of 0 to 4, m3s areindependently an integer of 0 to 3, and m4s are independently an integerof 0 to 5; when plural R₅₀₁s exist, the plural R₅₀₁s may be the same ordifferent;

wherein, in the formula (61),

at least one pair of R₆₀₁ and R₆₀₂, R₆₀₂ and R₆₀₃, and R₆₀₃ and R₆₀₄ arebonded with each other to form a divalent group represented by theformula (62);

at least one pair of R₆₀₅ and R₆₀₆, R₆₀₆ and R₆₀₇, and R₆₀₇ and R₆₀₈ arebonded with each other to form a divalent group represented by formula(63);

at least one of R₆₀₁ to R₆₀₄ that does not form the divalent grouprepresented by the formula 62), and R₆₁₁ to R₆₁₄ is a monovalent grouprepresented by the following formula (64);

at least one of R₆₀₅ to R₆₀₈ that do not form the divalent grouprepresented by the formula (63), and R₆₂₁ to R₆₂₄ is a monovalent grouprepresented by the following formula (64);

X₆₀₁ is an oxygen atom, a sulfur atom, or NR₆₀₉;

R₆₀₁ to R₆₀₈ that do not form the divalent group represented by theformulas (62) and (63) and that is not the monovalent group representedby the formula (64), R₆₁₁ to R₆₁₄ and R₆₂₁ to R₆₂₄ that are not themonovalent group represented by the formula (64), and R₆₀₉ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅).-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (64), Ar₆₀₁ and Ar₆₀₂ are independently

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

L₆₀₁ to L₆₀₃ are independently

-   a single bonded,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms,-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms, or-   a divalent linking group formed by bonding 2 to 4 above mentioned    groups;

wherein, in the formula (71),

A₇₀₁ ring and A₇₀₂ ring are independently

-   a substituted or unsubstituted aromatic hydrocarbon ring having 6 to    50 ring carbon atoms, or-   a substituted or unsubstituted heterocyclic ring having 5 to 50 ring    atoms;

One or more rings selected from the group consisting of A₇₀₁ ring andA₇₀₂ ring are bonded to the bond * of the structure represented by thefollowing formula (72);

wherein, in the formula (72),

A₇₀₃ rings are independently

-   a substituted or unsubstituted aromatic hydrocarbon ring having 6 to    50 ring carbon atoms, or-   a substituted or unsubstituted heterocyclic ring having 5 to 50 ring    atoms;-   X₇₀₁ is NR₇₀₃, C(R₇₀₄)(R₇₀₅), Si(R₇₀₆) (R₇₀₇), Ge(R₇₀₈) (R₇₀₉), O, S    or Se;

R₇₀₁ and R₇₀₂ are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring or do not form asubstituted or unsubstituted saturated or unsaturated ring;

R₇₀₁ and R₇₀₂ that do not form the substituted or unsubstituted,saturated or unsaturated ring, and R₇₀₃ to R₇₀₅ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —O—Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (81),

A₈₀₁ ring is a ring represented by the formula (82) which is fused to anadjacent ring at an arbitrary position;

A₈₀₂ ring is a ring represented by the formula (83) which is fused to anadjacent ring at an arbitrary position;

two bonds * bond to A₈₀₃ ring at an arbitrary position;

X₈₀₁ and X₈₀₂ are independently C(R₈₀₃)(R₈₄), Si(R₈₀₅)(R₅₀₆), an oxygenatom, or a sulfur atom;

A₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ringhaving 6 to 50 ring carbon atoms, or a substituted or unsubstitutedheterocyclic ring having 5 to 50 ring atoms; p Ar₈₀₁ is a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms, or asubstituted or unsubstituted monovalent heterocyclic group having 5 to50 ring atoms;

R₈₀₁ to R₈₀₆ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m801 and m802 are independently an integer of 0 to 2; when these are 2,plural R₈₀₁₅ or R₈₀₂s may be the same or different;

a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in theparenthese indicated by “3-a801” may be the same or different from eachother; when a801 is 2, Ar₈₀₁s may be the same or different from eachother.

-   2. An electronic apparatus provided with the organic    electroluminescence device according to the above 1.

According to the invention, an organic EL device having a long lifetime,and an electronic apparatus provided with the organic EL device can beprovided.

BRIEF DESCRIPTION OF THE DRAWINGS

The FIGURE is a view showing a schematic configuration of one embodimentof the organic EL device of the invention.

MODE FOR CARRYING OUT THE INVENTION [Definition]

In the present specification, a hydrogen atom means an atom includingisotopes different in the number of neutrons, namely, a protium, adeuterium and a tritium.

In the present specification, to a bondable position in which a symbolsuch as “R”, or “D” representing a deuterium atom is not specified in achemical formula, a hydrogen atom, that is, a light hydrogen atom, adeuterium atom, or a tritium atom is bonded thereto.

In the present specification, a term “ring carbon atoms” represents thenumber of carbon atoms among atoms forming a subject ring itself of acompound having a structure in which atoms are bonded in a ring form(for example, a monocyclic compound, a fused ring compound, across-linked compound, a carbocyclic compound or a heterocycliccompound). When the subject ring is substituted by a substituent, thecarbon contained in the substituent is not included in the number ofring carbon atoms. The same shall apply to the “ring carbon atoms”described below, unless otherwise noted. For example, a benzene ring has6 ring carbon atoms, a naphthalene ring has 10 ring carbon atoms, apyridine ring has 5 ring carbon atoms, and a furan ring has 4 ringcarbon atoms. Further, for example, a 9,9-diphenylfluorenyl group has 13ring carbon atoms, and a 9,9′-spirobifluorenyl group has 25 ring carbonatoms.

Further, when the benzene ring or the naphthalene ring is substituted byan alkyl group as a substituent, for example, the number of carbon atomsof the alkyl group is not included in the ring carbon atoms.

In the present specification, a term “ring atoms” represents the numberof atoms forming a subject ring itself of a compound having a structurein which atoms are bonded in a ring form (for example, a monocycle, afused ring and a ring assembly) (for example, a monocyclic compound, afused ring compound, a cross-linked compound, a carbocyclic compound ora heterocyclic compound). The term “ring atoms” does not include atomswhich do not form the ring (for example, a hydrogen atom whichterminates a bond of the atoms forming the ring) or atoms contained in asubstituent when the ring is substituted by the substituent. The sameshall apply to the “ring atoms” described below, unless otherwise noted.For example, a pyridine ring has 6 ring atoms, a quinazoline ring has 10ring atoms, and a furan ring has 5 ring atoms. A hydrogen atom bondedwith a carbon atom of the pyridine ring or the quinazoline ring or anatom forming the substituent is not included in the number of the ringatoms.

In the present specification, a term “XX to YY carbon atoms” in anexpression of “substituted or unsubstituted ZZ group having XX to YYcarbon atoms” represents the number of carbon atoms when the ZZ group isunsubstituted. The number of carbon atoms of a substituent when the ZZgroup is substituted is not included. Here, “YY” is larger than “XX”,and “XX” and “YY” each mean an integer of 1 or more.

In the present specification, a term “XX to YY atoms” in an expressionof “substituted or unsubstituted ZZ group having XX to YY atoms”represents the number of atoms when the ZZ group is unsubstituted. Thenumber of atoms of a substituent when the group is substituted is notincluded. Here, “YY” is larger than “XX”, and “XX” and “Yr each mean aninteger of 1 or more.

A term”unsubstituted” in the case of “substituted or unsubstituted ZZgroup” means that the ZZ group is not substituted by a substituent, anda hydrogen atom is bonded therewith. Alternatively, a term “substituted”in the case of “substituted or unsubstituted ZZ group” means that one ormore hydrogen atoms in the ZZ group are substituted by a substituent.Similarly, a term “substituted” in the case of “BB group substituted byan AA group” means that one or more hydrogen atoms in the BB group aresubstituted by the AA group.

Hereinafter, the substituent described herein will be described.

The number of the ring carbon atoms of the “unsubstituted aryl group”described herein is 6 to 50, preferably 6 to 30, and more preferably 6to 18, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted heterocyclicgroup” described herein is 5 to 50, preferably 5 to 30, and morepreferably 5 to 18, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkyl group”described herein is 1 to 50, preferably 1 to 20, and more preferably 1to 6, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkenyl group”described herein is 2 to 50, preferably 2 to 20, and more preferably 2to 6, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkynyl group”described herein is 2 to 50, preferably 2 to 20, and more preferably 2to 6, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted cycloalkylgroup” described herein is 3 to 50, preferably 3 to 20, and morepreferably 3 to 6, unless otherwise specified.

The number of the ring carbon atoms of the “unsubstituted arylene group”described herein is 6 to 50, preferably 6 to 30, and more preferably 6to 18, unless otherwise specified.

The number of the ring atoms of the “unsubstituted divalent heterocyclicgroup” described herein is 5 to 50, preferably 5 to 30, and morepreferably 5 to 18, unless otherwise specified.

The number of the carbon atoms of the “unsubstituted alkylene group”described herein is 1 to 50, preferably 1 to 20, and more preferably 1to 6, unless otherwise specified.

Specific examples (specific example group G1) of the “substituted orunsubstituted aryl group” described herein include an unsubstituted arylgroup and a substituted aryl group described below. (Here, a term“unsubstituted aryl group” refers to a case where the “substituted orunsubstituted aryl group” is the “unsubstituted aryl group,” and a term“substituted aryl group” refers to a case where the “substituted orunsubstituted aryl group” is the “substituted aryl group”. Hereinafter,a case of merely “aryl group” includes both the “unsubstituted arylgroup” and the “substituted aryl group”.

The “substituted aryl group” refers to a case where the “unsubstitutedaryl group” has a substituent, and specific examples thereof include agroup in which the “unsubstituted aryl group” has the substituent, and asubstituted aryl group described below. It should be noted that examplesof the “unsubstituted aryl group” and examples of the “substituted arylgroup” listed herein are only one example, and the “substituted arylgroup” described herein also includes a group in which a group in which“unsubstituted aryl group” has a substituent further has a substituent,and a group in which “substituted aryl group” further has a substituent,and the like.

An unsubstituted aryl group:

-   a phenyl group,-   a p-biphenyl group,-   a m-biphenyl group,-   an o-biphenyl group,-   a p-terphenyl-4-yl group,-   a p-terphenyl-3-yl group,-   a p-terphenyl-2-yl group,-   a m-terphenyl-4-yl group,-   a m-terphenyl-3-yl group,-   a m-terphenyl-2-yl group,-   an o-terphenyl-4-yl group,-   an o-terphenyl-3-yl group,-   an o-terphenyl-2-yl group,-   a 1-naphthyl group,-   a 2-naphthyl group,-   an anthryl group,-   a benzanthryl group,-   a phenanthryl group,-   a benzophenanthryl group,-   a phenalenyl group,-   a pyrenyl group,-   a chrysenyl group,-   a benzochrysenyl group,-   a triphenylenyl group,-   a benzotriphenylenyl group,-   a tetracenyl group,-   a pentacenyl group,-   a fluorenyl group,-   a 9,9′-spirobifluorenyl group,-   a benzofluorenyl group,-   a dibenzofluorenyl group,-   a fluoranethenyl group,-   a benzofluoranethenyl group, and-   a perylenyl group.

A substituted aryl group:

-   an o-tolyl group,-   a m-tolyl group,-   a p-tolyl group,-   a p-xylyl group,-   a m-xylyl group,-   an o-xylyl group,-   a p-isopropyl phenyl group,-   a m-isopropyl phenyl group,-   an o-isopropyl phenyl group,-   a p-t-butylphenyl group,-   a m-t-butylphenyl group,-   an o-t-butylphenyl group,-   a 3,4,5-trimethylphenyl group,-   a 9,9-dimethylfluorenyl group,-   a 9,9-diphenylfluorenyl group-   a 9,9-di(4-methylphenyl)fluorenyl group,-   a 9,9-di(4-isopropylphenyl)fluorenyl group,-   a 9,9-di(4-t-butylphenyl)fluorenyl group,-   a cyanophenyl group,-   a triphenylsilyiphenyl group,-   a trimethylsilylphenyl group,-   a phenylnaphthyl group, and-   a naphthylphenyl group.

The “heterocyclic group” described herein is a ring group having atleast one hetero atom in the ring atom. Specific examples of the heteroatom include a nitrogen atom, an oxygen atom, a sulfur atom, a siliconatom, a phosphorus atom and a boron atom.

The “heterocyclic group” described herein may be a monocyclic group, ora fused ring group.

The “heterocyclic group” described herein may be an aromaticheterocyclic group, or an aliphatic heterocyclic group.

Specific examples (specific example group G2) of the “substituted orunsubstituted heterocyclic group” include an unsubstituted heterocyclicgroup and a substituted heterocyclic group described below. (Here, theunsubstituted heterocyclic group refers to a case where the “substitutedor unsubstituted heterocyclic group” is the “unsubstituted heterocyclicgroup,” and the substituted heterocyclic group refers to a case wherethe “substituted or unsubstituted heterocyclic group” is the“substituted heterocyclic group”. Hereinafter, the case of merely“heterocyclic group” includes both the “unsubstituted heterocyclicgroup” and the “substituted heterocyclic group”.

The “substituted heterocyclic group” refers to a case where the“unsubstituted heterocyclic group” has a substituent, and specificexamples thereof include a group in which the “unsubstitutedheterocyclic group” has a substituent, and a substituted heterocyclicgroup described below. It should be noted that examples of the“unsubstituted heterocyclic group” and examples of the “substitutedheterocyclic group” listed herein are merely one example, and the“substituted heterocyclic group” described herein also includes a groupin which “unsubstituted heterocyclic group” which has a substituentfurther has a substituent, and a group in which “substitutedheterocyclic group” further has a substituent, and the like.

An unsubstituted heterocyclic group having a nitrogen atom:

-   a pyrrolyl group,-   an imidazolyl group,-   a pyrazolyl group,-   a triazolyl group,-   a tetrazolyl group,-   an oxazolyl group,-   an isoxazolyl group,-   an oxadiazolyl group,-   a thiazolyl group,-   an isothiazolyl group,-   a thiadiazolyl group,-   a pyridyl group,-   a pyridazinyl group,-   a pyrimidinyl group,-   a pyrazinyl group,-   a triazinyl group,-   an indolyl group,-   an isoindolyl group,-   an indolizinyl group,-   a quinolizinyl group,-   a quinolyl group,-   an isoquinolyl group,-   a cinnolyl group,-   a phthalazinyl group,-   a quinazolinyl group,-   a quinoxalinyl group,-   a benzimidazolyl group,-   an indazolyl group,-   a phenanthrolinyl group,-   a phenanthridinyl group-   an acridinyl group,-   a phenazinyl group,-   a carbazolyl group,-   a benzocarbazolyl group,-   a morpholino group,-   a phenoxazinyl group,-   a phenothiazinyl group,-   an azacarbazolyl group, and-   a diazacarbazolyl group.

An unsubstituted heterocyclic group having an oxygen atom:

-   a furyl group,-   an oxazolyl group,-   an isoxazolyl group,-   an oxadiazolyl group,-   a xanthenyl group,-   a benzofuranyl group, p0 an isobenzofuranyl group,-   a dibenzofuranyl group,-   a naphthobenzofuranyl group,-   a benzooxazolyl group,-   a benzisoxazolyl group,-   a phenoxazinyl group,-   a morpholino group,-   a dinaphthofuranyl group,-   an azadibenzofuranyl group,-   a diazadibenzofuranyl group,-   an azanaphthobenzofuranyl group, and-   a diazanaphthobenzofuranyl group.

An unsubstituted heterocyclic group having a sulfur atom;

-   a thienyl group,-   a thiazolyl group,-   an isothiazolyl group,-   a thiadiazolyl group,-   a benzothiophenyl group,-   an isobenzothiophenyl group,-   a dibenzothiophenyl group,-   a naphthobenzothiophenyl group,-   a benzothiazolyl group,-   a benzisothiazolyl group,-   a phenothiazinyl group,-   a dinaphthothiophenyl group,-   an azadibenzothiophenyl group,-   a diazadibenzothiophenyl group,-   an azanaphthobenzothiophenyl group, and-   a diazanaphthobenzothiophenyl group.

A substituted heterocyclic group having a nitrogen atom:

-   a (9-phenyl)carbazolyl group,-   a (9-biphenylypcarbazolyl group,-   a (9-phenyl)phenylcarbazolyl group,-   a (9-naphthyl)carbazolyl group,-   a diphenylcarbazol-9-yl group,-   a phenylearbazol-9-yl group,-   a methylbenzimidazolyl group,-   an ethylbenzimidazolyl group,-   a phenyltriazinyl group,-   a biphenylyitriazinyl group,-   a diphenyitriazinyl group,-   a phenylquinazolinyl group, and-   a biphenylylquinazolinyl group.

A substituted heterocyclic group having an oxygen atom:

-   a phenyldibenzofuranyl group,-   a methyldibenzofuranyl group,-   a t-butyldibenzofuranyl group, and-   a monovalent residue of spiro[9H-xanthene-9,9′-[9H]fluorene].

A substituted heterocyclic group having a sulfur atom.

-   a phenyldibenzothiophenyl group,-   a methyldibenzothiophenyl group,-   a t-butyldibenzothiophenyl group, and-   a monovalent residue of spiro[9H-thioxantene-9,9′-[9H]fluorene].

A monovalent group derived from the following unsubstituted heterocyclicring containing at least one of a nitrogen atom, an oxygen atom and asulfur atom by removal of one hydrogen atom bonded to the ring atomsthereof, and a monovalent group in which a monovalent group derived fromthe following unsubstituted heterocyclic ring has a substituent byremoval of one hydrogen atom bonded to the ring atoms thereof:

In the formulas (XY-1) to (XY-18), X_(A) and Y_(A) are independently anoxygen atom, a sulfur atom, NH or CH₂. However, at least one of X_(A)and Y_(A) is an oxygen atom, a sulfur atom or NH.

The heterocyclic ring represented by the formulas (XY-1) to (XY-18)becomes a monovalent heterocyclic group having a bond at an arbitraryposition.

An expression “the monovalent group derived from the unsubstitutedheterocyclic ring represented by the formulas (XY1) to (XY-18) has asubstituent” refers to a case where the hydrogen atom bonded with thecarbon atom which constitutes a skeleton of the formulas is substitutedby a substituent, or a state in which X_(A) or Y_(A) is NH or CH₂, andthe hydrogen atom in the NH or CH₂ is replaced with a substituent.

Specific examples (specific example group G3) of the “substituted orunsubstituted alkyl group” include an unsubstituted alkyl group and asubstituted alkyl group described below. (Here, the unsubstituted alkylgroup refers to a case where the “substituted or unsubstituted alkylgroup” is the “unsubstituted alkyl group,” and the substituted alkylgroup refers to a case where the “substituted or unsubstituted alkylgroup” is the “substituted alkyl group”). Hereinafter, the case ofmerely “alkyl group” includes both the “unsubstituted alkyl group” andthe “substituted alkyl group”.

The “substituted alkyl group” refers to a case where the “unsubstitutedalkyl group” has a substituent, arid specific examples thereof include agroup in which the “unsubstituted alkyl group” has a substituent, and asubstituted alkyl group described below. It should be noted thatexamples of the “unsubstituted alkyl group” and examples of the“substituted alkyl group” listed herein are merely one example, and the“substituted alkyl group” described herein also includes a group inwhich “unsubstituted alkyl group” has a substituent further has asubstituent, a group in which “substituted alkyl group” further has asubstituent, and the like.

An unsubstituted alkyl group:

-   a methyl group,-   an ethyl group,-   a n-propyl group,-   an isopropyl group,-   a n-butyl group,-   an isobutyl group,-   a s-butyl group, and-   a t-butyl group.

A substituted alkyl group:

-   a heptafluoropropyl group (including an isomer),-   a pentafluoroethyl group,-   a 2,2,2-trifluoroethyl group, and-   a trifluoromethyl group.

Specific examples (specific example group G4) of the “substituted orunsubstituted alkenyl group” include an unsubstituted alkenyl group anda substituted alkenyl group described below. (Here, the unsubstitutedalkenyl group refers to a case where the “substituted or unsubstitutedalkenyl group” is the “unsubstituted alkenyl group,” and the substitutedalkenyl group refers to a case where the “substituted or unsubstitutedalkenyl group” is the “substituted alkenyl group”). Hereinafter, thecase of merely “alkenyl group” includes both the “unsubstituted alkenylgroup” and the “substituted alkenyl group”.

The “substituted alkenyl group” refers to a case where the“unsubstituted alkenyl group” has a substituent, and specific examplesthereof include a group in which the “unsubstituted alkenyl group” has asubstituent, and a substituted alkenyl group described below. It shouldbe noted that examples of the “unsubstituted alkenyl group” and examplesof the “substituted alkenyl group” listed herein are merely one example,and the “substituted alkenyl group” described herein also includes agroup in which “unsubstituted alkenyl group” has a substituent furtherhas a substituent, a group in which “substituted alkenyl group” furtherhas a substituent, and the like.

An unsubstituted alkenyl group and a substituted alkenyl group:

-   a vinyl group,-   an allyl group,-   a 1-butenyl group,-   a 2-butenyl group,-   a 3-butenyl group,-   a 1,3-butanedienyl group,-   a 1-methylvinyl group,-   a 1-methylallyl group,-   a 1,1-dimethylallyl group,-   a 2-methylallyl group, and-   a 1,2-dimethylallyl group,

Specific examples (specific example group G5) of the “substituted orunsubstituted alkynyl group” include an unsubstituted alkynyl groupdescribed below. (Here, the unsubstituted alkynyl group refers to a casewhere the “substituted or unsubstituted alkynyl group” is the“unsubstituted alkynyl group”). Hereinafter, a case of merely “alkynylgroup” includes both the “unsubstituted alkynyl group” and the“substituted alkynyl group”.

The “substituted alkynyl group” refers to a case where the“unsubstituted alkynyl group” has a substituent, and specific examplesthereof include a group in which the “unsubstituted alkynyl group”described below has a substituent.

An unsubstituted alkynyl group:

-   an ethynyl group.

Specific examples (specific example group G6) of the “substituted orunsubstituted cycloalkyl group” described herein include anunsubstituted cycloalkyl group and a substituted cycloalkyl groupdescribed below. (Here, the unsubstituted cycloalkyl group refers to acase where the “substituted or unsubstituted cycloalkyl group” is the“unsubstituted cycloalkyl group,” and the substituted cycloalkyl grouprefers to a case where the “substituted or unsubstituted cycloalkylgroup” is the “substituted cycloalkyl group”). Hereinafter, a case ofmerely “cycloalkyl group” includes both the “unsubstituted cycloalkylgroup” and the “substituted cycloalkyl group”.

The “substituted cycloalkyl group” refers to a case where the“unsubstituted cycloalkyl group” a the substituent, and specificexamples thereof include a group in which the “unsubstituted cycloalkylgroup” has a substituent, and a substituted cycloalkyl group describedbelow. It should be noted that examples of the “unsubstituted cycloalkylgroup” and examples of the “substituted cycloalkyl group” listed hereinare merely one example, and the “substituted cycloalkyl group” describedherein also includes a group in which “unsubstituted cycloalkyl group”has a substituent further has a substituent, a group in which“substituted cycloalkyl group” further has a substituent, and the like.

An unsubstituted aliphatic ring group:

-   a cyclopropyl group,-   a cyclobutyl group,-   a cyclopentyl group,-   a cyclohexyl group,-   a 1-adamantyl group,-   a 2-adamantyl group,-   a 1-norbornyl group, and-   a 2-norbornyl group.

A substituted cycloalkyl group:

-   a 4-methylcyclohexyl group.

Specific examples (specific example group G7) of the group representedby —Si(R₉₀₁)(R₉₀₂)(R₉₀₃) described herein include

-   —Si(G1)(G1)(G1),-   —Si(G1)(G2)(G2),-   —Si(G1)(G1)(G2),-   —Si(G2)(G2)(G2),-   —Si(G3)(G3)(G3)-   —Si(G5)(G5)(G5) and-   —Si(G6)(G6)(G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocyclic group” described in the specific example groupG2.

G3 is the “alkyl group” described in the specific example group G3.

G5 is the “alkynyl group” described in the specific example group G5.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G8) of the group representedby —O—(R₉₀₄) described herein include

-   —O(G1),-   —O (G2),-   —O(G3) and-   —O(G6).

In which,

G1 is the “aryl group” described in the specific example group G1.

G2 is the “heterocyclic group” described in the specific example groupG2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G9) of the group representedby —S—(R₉₀₅) described herein include

-   —S(G1),-   —S(G2),-   —S(G3) and-   —S(G6).

In which,

G1 is the “aryl group” described in the specific example group G1,

G2 is the “heterocycle group” described in the specific example groupG2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G10) of the group representedby —N(R₉₀₆)(R₉₀₇) described herein include

-   —N(G1)(G1),-   —N(G2)(G2),-   —N(G1)(G2),-   —N(G3)(G3) and-   —N(G6) (G6).

In which,

G1 is the a “aryl group” described in the specific example group G1.

G2 is the ‘heterocycle group” described in the specific example groupG2.

G3 is the “alkyl group” described in the specific example group G3.

G6 is the “cycloalkyl group” described in the specific example group G6.

Specific examples (specific example group G11) of the “halogen atom”described herein include a fluorine atom, a chlorine atom, a bromineatom and an iodine atom.

Specific examples of the “alkoxy group” described herein include a grouprepresented by —O(G3), where G3 is the “alkyl group” described in thespecific example group G3. The number of carbon atoms of the“unsubstituted alkoxy group” are 1 to 50, preferably 1 to 30, and morepreferably 1 to18, unless otherwise specified.

Specific examples of the “alkylthio group” described herein include agroup represented by —S(G3), where G3 is the “alkyl group” described inthe specific example group G3. The number of carbon atoms of the“unsubstituted alkylthio group” are 1 to 50, preferably 1 to 30, andmore preferably 1 to 18, unless otherwise specified.

Specific examples of the “aryloxy group” described herein include agroup represented by —O(G1), where G1 is the “aryl group” described inthe specific example group G1. The number of ring carbon atoms of the“unsubstituted aryloxy group” are 6 to 50, preferably 6 to 30, and morepreferably 6 to 18, unless otherwise specified.

Specific examples of the “arylthio group” described herein include agroup represented by —S(G1), where G1 is the “aryl group” described inthe specific example group G1. The number of ring carbon atoms of the“unsubstituted arylthio group” are 6 to 50, preferably 6 to 30, and morepreferably 6 to 18, unless otherwise specified.

Specific examples of the “aralkyl group” described herein include agroup represented by -(G3)-(G1), where G3 is the “alkyl group” describedin the specific example group G3, and G1 is the “aryl group” describedin the specific example group G1. Accordingly, the “aralkyl group” isone embodiment of the “substituted alkyl group” substituted by the “arylgroup”. The number of carbon atoms of the “unsubstituted aralkyl group,”which is the “unsubstituted alkyl group” substituted by the“unsubstituted aryl group,” are 7 to 50, preferably 7 to 30, and morepreferably 7 to 18, unless otherwise specified.

Specific example of the “aralkyl group” include a benzyl group, a1-phenylethyl group, a 2-phenylethyl group, a 1-phenylisopropyl group, a2-phenylisopropyl group, a phenyl-t-butyl group, an α-naphthylmethylgroup, a 1-α-naphthylethyl group, a 2-α-naphthylethyl group, a1-α-naphthylisopropyl group, a 2-α-naphthylisopropyl group, aβ-naphthylmethyl group, a 1-β-naphthylethyl group, a 2-β-naphthylethylgroup, a 1-β-naphthylisopropyl group, and a 2-β-naphthylisopropyl group.

The substituted or unsubstituted aryl group described herein is, unlessotherwise specified, preferably a phenyl group, a p-biphenyl group, am-biphenyl group, an o-biphenyl group, a p-terphenyl-4-yl group, ap-terphenyl-3-yl group, a p-terphenyl-2-yl group, a m-telphenyl-4-ylgroup, a m-terphenyl-3-yl group, a m-terphenyl-2-yl group, ano-terphenyl-4-yl group, an o-terphenyl-3-yl group, an o-terphenyl-2-ylgroup, a 1-naphthyl group, a 2-naphthyl group, an anthryl group, aphenanthryl group, a pyrenyl group, a chrysenyl group, a triphenylenylgroup, a fluorenyl group, a 9,9′-spirobifluorenyl group, a9,9-diphenylfluorenyl group, or the like.

The substituted or unsubstituted heterocyclic group described herein is,unless otherwise specified, preferably a pyridyl group, a pyrimidinylgroup, a triazinyl group, a quinolyl group, an isoquinolyl group, aquinazolinyl group, a benzimidazolyl group, a phenanthrolinyl group, acarbazolyl group (a 1-carbazolyl group, a 2-carbazolyl group, a3-carbazolyl group, a 4-carbazolyl group, or a 9-carbazolyl group), abenzocarbazolyl group, an azacarbazolyl group, a diazacarbazolyl group,a dibenzofuranyl group, a naphthobenzofuranyl group, anazadibenzofuranyl group, a diazadibenzofuranyl group, adibenzothiophenyl group, a naphthobenzothiophenyl group, anazadibenzothiophenyl group, a diazadibenzothiophenyl group, a(9-phenyl)carbazolyl group (a (9-phenyl)carbazol-1-yl group, a(9-phenyl)carbazol-2-yl group, a (9-phenyl)carbazol-3-yl group, or a(9-phenyl)carbazol-4-yl group), a (9-biphenylyl)carbazolyl group, a(9-phenyl)phenylcarbazolyl group, a diphenylcarbazole-9-yl group, aphenylcarbazol-9-yl group, a phenyltriazinyl group, abiphenylyltriazinyl group, diphenyltriazinyl group, aphenyldibenzofuranyl group, a phenyldibenzothiophenyl group, anindrocarbazolyl group, a pyrazinyl group, a pyridazinyl group, aquinazolinyl group, a cinnolinyl group, a phthalazinyl group, aquinoxalinyl group, a pyrrolyl group, an indolyl group, apyrrolo[3,2,1-jk]carbazolyl group, a furanyl group, a benzofuranylgroup, a thiophenyl group, a benzothiophenyl group, a pyrazolyl group,an imidazolyl group, a benzimidazolyl group, a triazoyl group, anoxazolyl group, a benzoxazolyl group, a thiazolyl group, abenzothiazolyl group, an isothiazolyl group, a benzisothiazolyl group, athiadiazolyl group, an isoxazolyl group, a benzisoxazolyl group, apyrrolidinyl group, a piperidinyl group, a piperazinyl group, animidazolidinyl group, an indro[3,2,1-jk]carbazolyl group, adibenzothiophenyl group, or the like.

The dibenzofuranyl group and the dibenzothiophenyl group as describedabove are specifically any group described below, unless otherwisespecified.

In the formulas (XY-76) to (XY-79), X_(B) is an oxygen atom or a sulfuratom.

The substituted or unsubstituted alkyl group described herein is, unlessotherwise specified, preferably a methyl group, an ethyl group, a propylgroup, an isopropyl group, a n-butyl group, an isobutyl group, a t-butylgroup, or the like.

The “substituted or unsubstituted arylene group” described herein refersto a group in which the above-described “aryl group” is converted intodivalence, unless otherwise specified. Specific examples (specificexample group G12) of the “substituted or unsubstituted arylene group”include a group in which the “aryl group” described in the specificexample group G1 is converted into divalence. Namely, specific examples(specific example group G12) of the “substituted or unsubstitutedarylene group” refer to a group derived from the “aryl group” describedin specific example group G1 by removal of one hydrogen atom bonded tothe ring carbon atoms thereof.

Specific examples (specific example group G13) of the “substituted orunsubstituted divalent heterocyclic group” include a group in which the“heterocyclic group” described in the specific example group G2 isconverted into divalence. Namely, specific examples (specific examplegroup G13) of the “substituted or unsubstituted divalent heterocyclicgroup” refer to a group derived from the “heterocyclic group” describedin specific example group G2 by removal of one hydrogen atom bonded tothe ring atoms thereof.

Specific examples (specific example group G14) of the “substituted orunsubstituted alkylene group” include a group in which the “alkyl group”described in the specific example group G3 is converted into divalence.Namely, specific examples (specific example group G14) of the“substituted or unsubstituted alkylene group” refer to a group derivedfrom the “alkyl group” described in specific example group G3 by removalof one hydrogen atom bonded to the carbon atoms constituting the alkanestructure thereof.

The substituted or unsubstituted arylene group described herein is anygroup described below, unless otherwise specified.

In the formulas (XY-20) to (XY-29), (XY-83) and (XY-84), R₉₀₈ is asubstituent.

Then, m901 is an integer of 0 to 4, and when m901 is 2 or more, aplurality of R₉₀₈ may be the same with or different from each other.

In the formulas (XY-30) to (XY-40), R₉₀₉ is independently a hydrogenatom or a substituent. Two of R₉₀₉ may be bonded with each other througha single bond to form a ring.

In the formulas (XY-41) to (XY-46), R₉₁₀ is a substituent.

Then, m902 is an integer of 0 to 6. Men m902 is 2 or more, a pluralityof R₉₁₀ may be the same with or different from each other.

The substituted or unsubstituted divalent heterocyclic group describedherein is preferably any group described below, unless otherwisespecified.

In the formulas (XY-50) to (XY-60), R₉₁₁ is a hydrogen atom or asubstituent.

In the formulas (XY65) to (XY-75), X_(B) is an oxygen atom or a sulfuratom.

Herein, a case where “one or more sets of two or more groups adjacent toeach other are bonded with each other to form a substituted orunsubstituted and saturated or unsaturated ring” will be described bytaking, as an example, a case of an anthracene compound represented bythe following formula (XY-80) in which a mother skeleton is ananthracene ring.

For example, two adjacent to each other into one set when “one or moresets of two or more groups adjacent to each other are bonded with eachother to form the ring” among R₉₂₁ to R₉₃₀ include R₉₂₁ and R₉₂₂, R₉₂₂and R₉₂₃, R₉₂₃ and R₉₂₄, R₉₂₄ and R₉₃₀, R₉₃₀ and R₉₂₅, R₉₂₅ and R₉₂₆,R₉₂₆ and R₉₂₇, R₉₂₇ and R₉₂₈, R₉₂₃ and R₉₂₉, and R₉₂₉ and R₉₂₁.

The above-described “one or more sets” means that two or more sets oftwo groups adjacent to each other may simultaneously form the ring. Forexample, a case where R₉₂₁ and R₉₂₂ are bonded with each other to form aring A, and simultaneously R₉₂₅ and R₉₂₆ are bonded with each other toform a ring B is represented by the following formula (XY-81).

A case where “two or more groups adjacent to each other” form a ringmeans that, for example, R₉₂₁ and R₉₂₂ are bonded with each other toform a ring A, and R₉₂₂ and R₉₂₃ are bonded with each other to form aring C. A case where the ring A and ring C sharing R₉₂₂ are formed, inwhich the ring A and the ring C are fused to the anthracene motherskeleton by three of R₉₂₁ to R₉₂₃ adjacent to each other, is representedby the following (X-82).

The rings A to C forged in the formulas (XY-81) and (XY-82) are asaturated or unsaturated ring.

A term “unsaturated ring” means an aromatic hydrocarbon ring or anaromatic heterocyclic ring. A term “saturated ring” means an aliphatichydrocarbon ring or an aliphatic heterocyclic ring.

For example, the ring A formed-by R₉₂₁ and R₉₂₂ being bonded with eachother, represented by the formula (XY-81), means a ring formed by acarbon atom of the anthracene skeleton bonded with R₉₂₁, a carbon atomof the anthracene skeleton bonded with R₉₂₂, and one or more arbitraryelements. Specific examples include, when the ring A is formed by R₉₂₁and R₉₂₂, a case where an unsaturated ring is formed of a carbon atom ofan anthracene skeleton bonded with R_(921,) a carbon atom of theanthracene skeleton bonded with R₉₂₂, and four carbon atoms, in which aring formed by R₉₂₁ and R₉₂₂ is formed into a benzene ring. Further,when a saturated ring is formed, the ring is formed into a cyclohexanering.

Here, “arbitrary elements” are preferably a C element, a N element, an Oelement and a S element. In the arbitrary elements (for example, a caseof the C element or the N element), the bond(s) that is(are) notinvolved in the formation of the ring may be terminated by a hydrogenatom, or may be substituted by an arbitrary substituent. When the ringcontains the arbitrary elements other than the C element, the ring to beformed is a heterocyclic ring.

The number of “one or more arbitrary elements” forming the saturated orunsaturated ring is preferably 2 or more and 15 or less, more preferably3 or more and 12 or less, and further preferably 3 or more and 5 orless.

As specific examples of the aromatic hydrocarbon ring, a structure inwhich the aryl group described in specific example group G1 isterminated with a hydrogen atom may be mentioned.

As specific examples of the aromatic heterocyclic ring, a structure inwhich the aromatic heterocyclic group described in specific examplegroup G2 is terminated with a hydrogen atom may be mentioned.

As specific examples of the aliphatic hydrocarbon ring, a structure inwhich the cycloalkyl group described in specific example group G6 isterminated with a hydrogen atom may be mentioned.

When the above-described “saturated or unsaturated ring” has asubstituent, the substituent is an “arbitrary substituent” as describedbelow, for example. When the above-mentioned “saturated or unsaturatedring” has a substituent, specific examples of the substituent refer tothe substituents described in above-mentioned “the substituent describedherein”.

In one embodiment of the present specification, the substituent(hereinafter, referred to as an “arbitrary substituent” in severalcases) in the case of the “substituted or unsubstituted” is a groupselected from the group consisting of

-   an unsubstituted alkyl group having 1 to 50 carbon atoms,-   an unsubstituted alkenyl group having 2 to 50 carbon atoms,-   an unsubstituted alkynyl group having 2 to 50 carbon atoms,-   an unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅)-   —N(R₉₀₆)(R₉₀₇)-   wherein,-   R₉₀₁ to R₉₀₇ are independently-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and-   when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇    may be the same with or different from each other,-   a halogen atom, a cyano group, a nitro group,-   an unsubstituted aryl group having 6 to 50 ring carbon atoms, and-   an unsubstituted monovalent heterocyclic group having 5 to 50 ring    atoms.

In one embodiment, the substituent in the case of “substituted orunsubstituted” is a group selected from the group consisting of

-   an alkyl group having 1 to 50 carbon atoms,-   an aryl group having 6 to 50 ring carbon atoms, and-   a monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, the substituent in the case of “substituted orunsubstituted” is a group selected from the group consisting of

-   an alkyl group having 1 to 18 carbon atoms,-   an aryl group having 6 to 18 ring carbon atoms, and-   a monovalent heterocyclic group having 5 to 18 ring atoms.

Specific examples of each group of the arbitrary substituent describedabove are as described above.

Herein, unless otherwise specified, the saturated or unsaturated ring(preferably substituted or unsubstituted and saturated or unsaturatedfive-membered or six-membered ring, more preferably a benzene ring) maybe formed by the arbitrary substituents adjacent to each other.

Herein, unless otherwise specified, the arbitrary substituent mayfurther have the substituent. Specific examples of the substituent thatthe arbitrary substituent further has include to the ones same as thearbitrary substituent described above.

[Organic EL Device]

The organic EL device according to one aspect of the invention comprisesa cathode, an anode and an emitting layer disposed between the cathodeand the anode, and it is characterized in that the emitting layercomprises a compound represented by the following formula (1) and one ormore compounds selected from the group consisting of compoundsrepresented by formulas (11), (21), (31), (41), (51), (61), (71) and(81).

Each compound is described later.

The organic EL device according to one aspect of the invention exhibitshigh device performance by possessing the above-mentioned constitution.Specifically, it is possible to provide an organic EL device with longerlife.

According to one aspect of the present invention, a method for improvinga performance of an organic EL device can also be provided, the methodis characterized in that the compound represented by the formula (1) andone or more compounds selected from the group consisting of the formulas(11) to (81) are used in combination in the emitting layer of theorganic EL device. Specifically, the method can improve an organic ELdevice performance as compared with the case where a compound having thesame structure as formula (1) except that only protium atoms arecontained as hydrogen atoms (hereinafter also referred to as “protiumcompound”) is used as a host material. The case where the protiumcompound is used means that a host material in an emitting layerconsists essentially of the protium compound (the ratio of the protiumcompound to the sum of the protium compound and the compound representedby formula (1) is 90 mol % or more, 95 mol % or more, or 99 mol % ormore).

That is, it is possible to increase a performance of an organic ELdevice by, instead of a protium compound or in addition to a protiumcompound, using a compound obtained by replacing at least one protiumatoms on an anthracene skeleton of the protium compound with a deuteriumatom (a compound represented by formula (1)) as a host material.

A schematic outline of the organic EL device of one aspect of theinvention is explained by reference to the FIGURE.

The organic EL device 1 according to one aspect of the inventioncomprises substrate 2, anode 3, emitting layer 5, cathode 10, organiclayer 4 disposed between the anode 3 and the emitting layer 5, andorganic layer 6 disposed between the emitting layer 5 and the cathode10.

The compound represented by the formula (1) and one or more compoundsselected from a group consisting of compounds represented by the formula(11), (21), (31), (41), (51), (61), (71) and (81) are contained inemitting layer 5 disposed between the anode 3 and the cathode 10. Eachcompound contained in the emitting layer 5 may be used singly or incombination of two or more,

(Compound Represented by Formula (1))

The compound represented by the formula (1) is explained below,

wherein in the formula (1),

R₁ to R_(a) are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted acyl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ maybe the same with or different from each other;

at least one of R₁ to R₈ is a deuterium atom;

two or more adjacent groups of R₁ to R₄ and two or more adjacent groupsof R₅ to R₈ do not form a ring;

L₁ and L₂ are independently

-   a single bond,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms;

Ar₁ is

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

Ar₂ is a monovalent group represented by the following formula (2), (3)or (4);

wherein in the formulas (2) to (4),

one or more pairs of two adjacent groups of R₁₅ to R₂₀ are bonded witheach other to form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

when one or more pairs of two adjacent groups of R₁₅ to R₂₀ are notbonded with each other and do not form a substituted or unsubstituted,saturated or unsaturated ring, one of R₁₁ to R₂₀ is a single bondbonding to L₂;

when one or more pairs of two adjacent groups of R₁₅ to R₂₀ are bondedwith each other to form a substituted or unsubstituted, saturated orunsaturated ring, one of R₁₅ to R₂₀ which does not form a substituted orunsubstituted, saturated or unsaturated ring and R₁₁ to R₁₄ is a singlebond bonding to L₂;

R₁₁ to R₂₀ that do not form the substituted or unsubstituted, saturatedor unsaturated ring and that are not a single bond bonding to L₂ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

All of R₁ to R₈ may be deuterium atoms or a part of them (e,g., one, twoor more of R₁ to R₈) may be deuterium atoms.

R₁ to R₈ that are not deuterium atoms are preferably hydrogen atoms(protium atoms).

In one embodiment, at least one hydrogen atom contained in one or moregroups selected from a group consisting of L₁ and L₂ is a deuteriumatom. In more detail, in one embodiment, one or more groups selectedfrom the group consisting of L₁ and L₂ are an unsubstituted arylenegroup having 6 to 30 ring carbon atoms in which at least one hydrogenatom is a deuterium atom, or an unsubstituted divalent heterocyclicgroup having 5 to 30 ring atoms in which at least one hydrogen atom is adeuterium atom.

In one embodiment, L₁ and L₂ are independently a single bond, or asubstituted or unsubstituted arylene group having 6 to 14 ring carbonatoms. It is preferable that at least one of L₁ and L₂ is a single bond.

In one embodiment, any one of R₁₁ to R₁₄ in formulas (2) to (4) is asingle bond bonding to L₂.

In one embodiment, one or more pairs of two adjacent groups of R₁₅ toR₂₀ in formulas (2) to (4) are not bonded with each other and do notform a substituted or unsubstituted, saturated or unsaturated ring.

In one embodiment, among R₁₁ to R₂₀ in the formulas (2) to (4), thosewhich are not a single bond bonding to L₂ and do not contribute to ringformation are preferably hydrogen atoms.

In one embodiment, among R₁₁ to R₂₀ in the formulas (2) to (4), at leastone which is not a single bond bonding to L₂ and does not contribute toring formation is a deuterium atom.

In one embodiment, at least one hydrogen atom contained in one or moreAr₁ is a deuterium atom. In more detail, in one embodiment, Ar₁ is anunsubstituted aryl group having 6 to 50 ring carbon atoms in which atleast one hydrogen atom is a deuterium atom, or an unsubstitutedmonovalent heterocyclic group having 5 to 50 ring atoms in which atleast one hydrogen atom is a deuterium atom.

Existence of a deuterium atom in the compound is confirmed by MassSpectrometry or ¹H-NMR Spectrometry. The bonding position of a deuteriumatom in the compound is identified by ¹H-NMR Spectrometry. In concreteterms, it is confirmed as follows.

If it is identified that, by Mass Spectrometry, a molecular weight of atarget compound is greater by “one” than a molecular weight of acorresponding compound in which all hydrogen atoms are protium atoms, itis confirmed that one deuterium atom exists in the target compound.Further, the number of deuterium atoms in a molecule can be confirmed byan integration value obtained by ¹H-NMR analysis on the target compound,since no signal is observed by performing ¹H-NMR analysis on a deuteriumatom. The bonding position of a deuterium can be identified byperforming ¹H-NMR analysis on the target compound and assigning signals.

In the organic EL device according to one aspect of the invention, thecontent ratio of the protium compound to the total of the compoundrepresented by formula (1) and the protium compound in the emittinglayer is preferably 99 mol % or less. The content ratio of the protiumcompound is confirmed by Mass Spectrometry.

In one embodiment, the emitting layer of the organic EL device accordingto one aspect of the invention includes the compound represented by theformula (1) and a protium compound, and the content ratio of the formerto the total thereof is 30 mol % or more, 50 mol % or more, 70 mol % ormore, 90 mol % or more, 95 mol % or more, 99 mol % or more, or 100 mol%.

An is preferably a substituted or unsubstituted aryl group having 6 to50 ring carbon atoms, more preferably selected from groups representedby the following formulas (a1) to (a4).

wherein in the formulas (a1) to (a4), p * is a single bond bonding toL₁;

R₂₁ is

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   13 N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m1 is an integer of 0 to 4;

m2 is an integer of 0 to 5;

m3 is an integer of 0 to 7;

when each of m1 to m3 is 2 or more, the plural R₂₁s may be the same ordifferent; and

when each of m1 to m3 is 2 or more, adjacent plural R₂₁s are bonded witheach other to form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring.

Preferably, L₁ and L₂ are independently a single bond, or a substitutedor unsubstituted arylene group having 6 to 14 ring carbon atoms. It ispreferable that at least one of L₁ and L₂ is a single bond.

In one embodiment, the compound represented by the formula (1) is acompound represented by any one of following formulas (1-1) to (1-3).

wherein in the formulas (1-1) to (1-3) R₁ to R₈, Ar₁, L₁ and L₂ are asdefined in the formula (1).

In one embodiment, the compound represented by the formula (1) is acompound represented by any one of following formulas (1-11) to (1-13).

wherein in the formulas (1-11) to (1-13), Ar₁, L₁ and L₂ are as definedin the formula (1).

In one embodiment, the compound represented by the formula (1) isrepresented by the following formula (1A):

wherein in the formula (1A),

R_(1A) to R_(8A) are independently a hydrogen atom, and at least one ofR_(1A) to R_(8A) is a deuterium atom;

L_(1A) and L_(2A) are independently a single bond, an unsubstitutedphenylene group, or an unsubstituted naphthylene group;

Ar_(1A) is a substituted or unsubstituted phenyl group or a substitutedor unsubstituted naphthyl group, and the substituent for Ar_(1A) is aphenyl group;

Ar_(2A) is a monovalent group represented by the following formula (2A),(3A) or (4A):

wherein in the formulas (2A) to (4A),

any one of R₁₃ to R_(14A) is a single bond bonding to L_(2A); andR_(11A), R_(12A), R_(15A) to R_(20A), as well as R_(13A) to R_(14A) thatare not a single bond bonding to L_(2A) are independently a hydrogenatom or an unsubstituted aryl group including 6 to 50 ring carbon atoms.

In one embodiment, in the formula (1A), at least two of R_(1A) to R_(8A)are deuterium atoms.

In one embodiment, in the formula (1A), R_(1A) to R_(8A) are alldeuterium atoms.

In one embodiment, in the formula (1A), at least one hydrogen atomcontained in Ar_(1A) is a deuterium atom.

In one embodiment, in the formula (1A), R_(11A), R_(12A), R_(15A) toR_(20A), as well as R_(13A) to R_(14A) that are not a single bondbonding to L_(2A) are hydrogen atoms.

In one embodiment, in the formula (1A), at least one of R_(11A),R_(12A), R_(15A) to R_(20A), as well as R_(13A) to R_(14A) that are nota single bond bonding to L_(2A) is a deuterium atoms.

The compound represented by the formula (1) can be synthesized inaccordance with the synthesis process described in Examples by usingpublicly known alternative reactions or materials corresponding to atarget compound.

Examples of the compound represented by formula (1) include thefollowing compounds. In the following example compounds, D represents adeuterium atom.

(Compound Represented by Formula (11))

The compound represented by the formula (11) is explained below,

In the formula (11),

one or more pairs of two or more adjacent groups of R₁₀₁ to R₁₁₀ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

at least one of R₁₀₁ to R₁₁₀ is a monovalent group represented by theformula (12);

R₁₀₁ to R₁₁₀ to that do not form the substituted or unsubstituted,saturated or unsaturated ring and that are not a monovalent grouprepresented by the following formula (12) are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (12), Ar₁₀₁ and Ar₁₀₂ are independently

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

L₁₀₁ to L₁₀₃ are independently

-   a single bonded,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms;

In the formula (11), it is preferable that two of R₁₀₁ to R₁₁₀ are thegroup represented by the formula (12),

In one embodiment, the compound represented by the formula (11) isrepresented by the following formula (13):

wherein in the formula (13), R₁₁₁ to R₁₁₈ are the same as R₁₀₁ to R₁₁₀that is not a monovalent group represented by the formula (12) in theformula (11). Ar₁₀₁, Ar₁₀₂, L₁₀₁, L₁₀₂ and L₁₀₃ are as defined in theformula (12).

In the formula (11), L₁₀₁ is preferably a single bond and L₁₀₂ and L₁₀₃are preferably a single bond.

In one embodiment, the compound represented by the formula (11) isrepresented by the formula (14) or (15).

wherein in the formula (14), R₁₁₁ to R₁₁₈ are as defined in the formula(13). Ar₁₀₁, Ar₁₀₂, L₁₀₂ and L₁₀₃ are as defined in the formula (12).

wherein in the formula (15), R₁₁₁ to R₁₁₈ are as defined in the formula(13). Ar₁₀₁ and Ar₁₀₂ are as defined in the formula (12),

In the formula (11) and formula (12), it is preferable that at least oneof Ar₁₀₁ and Ar₁₀₂ the group represented by the following formula (16).

wherein in the formula (16),

X₁₀₁ is an oxygen atom or a sulfur atom;

One or more pairs of two or more adjacent groups of R₁₂₁ to R₁₂₇ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring:

R₁₂₁ to R₁₂₇ that do not form the substituted or unsubstituted,saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

It is preferable that X₁₀₁ is an oxygen atom.

It is preferable that at least one of R₁₂₁ to R₁₂₇ is

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

It is preferable that in the formula (11) and formula (12), Ar₁₀₁ is agroup represented by the formula (16) and Ar₁₀₂ is a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (11) isrepresented by the following formula (17).

wherein in the formula (17), R₁₁₁ to R₁₁₈ are as defined in the formula(13), and R₁₂₁ to R₁₂₇ are as defined in the formula (16);

R₁₃₁ to R₁₃₅ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and-   R₉₀₁ to 8907 are as defined in the formula (1).

As the compound represented by the formula (11), the following compoundscan be given as specific examples, for example. In the following examplecompounds, Me represents a methyl group.

(Compound Represented by Formula (21))

The compound represented by the formula (21) is explained below.

-   wherein, in the formula (21),

Zs are independently CR_(a) or N;

A1 ring and A2 ring are independently a substituted or unsubstitutedaromatic hydrocarbon ring having 6 to 50 ring carbon atoms, or asubstituted or unsubstituted heterocyclic ring having 5 to 50 ringatoms;

when plural R_(a)s exist, one or more pairs of two or more adjacentgroups of R_(a) are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

when plural R_(b)s exist, one or more pairs of two or more adjacentgroups of R_(b) are bonded with each other to foul a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

when plural R_(c)s exist, one or more pairs of two or more adjacentgroups of R_(c) are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring;

n21 and n22 are independently an integer of 0 to 4;

R_(a) to R_(c) that do not form the substituted or unsubstituted,saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;-   R₉₀₁ to R₉₀₇ are as defined in the formula (1);

The “aromatic hydrocarbon ring” of A1 ring and A2 ring has the samestructure as the compound obtained by introducing a hydrogen atom intothe “aryl group” described above.

The “aromatic hydrocarbon ring” of the A1 ring and the A2 ring containstwo carbon atoms in the fused bicyclic structure at the center of theformula (21) as ring atoms. Examples of “substituted or unsubstitutedaromatic hydrocarbon ring having 6 to 50 ring carbon atoms” includecompounds in which a hydrogen atom is introduced into the “aryl group”described in the example group G1.

The “heterocyclic ring” of A1 ring and A2 ring has the same structure asthe compound obtained by introducing a hydrogen atom into the“heterocyclic group” described above. The “heterocyclic ring” of the A1ring and the A2 ring contains two carbon atoms in the fused bicyclicstructure at the center of the formula (21) as ring atoms. Examples of“substituted or unsubstituted heterocyclic ring having 5 to 50 ringatoms” include compounds in which a hydrogen atom is introduced into the“heterocyclic group” described in the example group G2.

R_(b) is bonded to one of carbon atoms which form the aromatichydrocarbon ring of A1 ring, or one of atoms which form the heterocycleof A1 ring.

R_(c) is bonded to one of carbon atoms which form the aromatichydrocarbon ring of A2 ring, or one of atoms which form the heterocycleof A2 ring.

It is preferable that at least one (preferably two) of R_(a) to R_(c) isa group represented by the following formula (21a).

-L₂₀₁-Ar₂₀₁   (21a)

wherein in the formula (21a),

L₂₀₁ is

-   a single bond,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted bivalent heterocyclic group having 5    to 30 ring atoms;

Ar₂₀₁ is

-   a substituted or unsubstituted arylene group having 6 to 50 ring    carbon atoms,-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms, or-   a group represented by the following formula (21b):

wherein in the formula (21b),

L₂₁₁ and L₂₁₂ are independently

-   a single bond,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms;

Ar₂₁₁ and Ar₂₁₂ are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring; and

Ar₂₁₁ and Ar₂₁₂ that do not form a substituted or unsubstituted,saturated or unsaturated ring are independently

a substituted or unsubstituted aryl group having 6 to 50 ring carbonatoms or

a substituted or unsubstituted monovalent heterocyclic group having 5 to50 ring atoms.

In one embodiment, the compound represented by the formula (21) isrepresented by the following formula (22).

wherein in the formula (22),

one or more pairs of two or more adjacent groups of R₂₀₁ to R₂₁₁ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstitutedsaturated or unsaturated ring;

R₂₀₁ to R₂₁₁ that do not form the substituted or unsubstituted,saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —S—(R₉₀₄),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1))

It is preferable that at least one (preferably two) of R₂₀₁ to R₂₁₁ isthe group represented by the formula (21a). It is preferable that R₂₀₄and R₂₁₁ are the group represented by the formula (21a).

In one embodiment, the compound represented by the formula (21) is acompound obtained by bonding the structure represented by the followingformula (21-1) or (21-2) to A1 ring. In one embodiment, the compoundrepresented by the formula (22) is a compound obtained by bonding thestructure represented by the following formula (21-1) or (21-2) to thering to which R₂₀₄ to R₂₀₇ bonds to.

wherein in the formula (21-1), two bonds shown by independently bond toa ring carbon atom in the aromatic hydrocarbon ring or a ring atom inthe heterocyclic group in A1 ring in the formula (21), or bond to one ofR₂₀₄ to R₂₀₇ in the formula (22);

wherein in the formula (21-2), three bonds shown by * independently bondto a ring carbon atom in the aromatic hydrocarbon ring or a ring atom inthe heterocyclic group in A1 ring in the formula (21), or bond to one ofR₂₀₄ to R₂₀₇ in the formula (22);

One or more pairs of two or more adjacent groups of R₂₂₁ to R₂₂₇ andR₂₂₁ to R₂₃₉ are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted, saturated or unsaturated ring:

R₂₂₁ to R₂₂₇ and R₂₃₁ to R₂₃₉ that do not form the substituted orunsubstituted, saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and-   R₉₀₁ to R₉₀₇ are as defined in the formula (1)

In one embodiment, the compound represented by the formula (21) is acompound represented by the following formula (21-3), (21-4), or (21-5).

wherein in the formulas (21-3), (21-4) and (21-5),

A1 ring is as defined in the formula (21);

-   R₂₄₀₁ to R₂₄₀₇ are the same as R₂₂₁ to R₂₂₇ in the formulas (21-1)    and (21-2);-   R₂₄₁₀ to R₂₄₁₇ are the same as R₂₀₁ to R₂₁₁ in the formula (22); and    the two R₂₄₁₇s may be the same or different.

In one embodiment, the substituted or unsubstituted aromatic hydrocarbonring having 6 to 50 ring carbon atoms of A1 ring in the formula (21-5)is a substituted or unsubstituted napthalene ring, or a substituted orunsubstituted fluorene ring.

In one embodiment, the substituted or unsubstituted heterocycle having 5to 50 ring atoms of Al ring in the formula (21-5) is a substituted orunsubstituted dibenzofuran ring, a substituted or unsubstitutedcarbazole ring, or a substituted or unsubstituted dibenzothiophene ring.

In one embodiment, the compound represented by the formula (21) or (22)is selected from the group consisting of the compounds represented bythe following formulas (21-6-1) to (21-6-7).

wherein in the formulas (21-6-1) to (21-6-7),

R₂₄₂₁ to R₂₄₂₇ are the same as R₂₂₁ to R₂₂₇ in the formulas (21-1) and(21-2);

R₂₄₃₀ to R₂₄₃₇ and R₂₄₄₁ to R₂₄₄₄ are the same as R₂₀₁ to R₂₁₁ in theformula (22);

X is O, NR₉₀₁, or C(R₉₀₂) (R₉₀₃); and

R₉₀₁ to R₉₀₃ are as defined in the formula (1).

In one embodiment, in the compound represented by the formula (22), oneor more pairs of two or more adjacent groups of R₂₀₁ to R₂₁₁ are bondedwith each other to form a substituted or unsubstituted, saturated orunsaturated ring. This embodiment is described in the following formula(25).

(Compound Represented by Formula (25))

The compound represented by the formula (25) is explained below.

wherein in the formula (25),

two or more pairs selected from a group consisting of R₂₅₁ and R_(252,)R₂₅₂ and R₂₅₃, R₂₅₄ and R₂₅₅, R₂₅₅ and R₂₅₆, R₂₅₆ and R₂₅₇, R₂₅₈ andR₂₅₉, R₂₅₉ and R₂₆₀, and R₂₆₀ and R₂₆₁ bond with each other to form asubstituted or unsubstituted, saturated or unsaturated ring;

Provided that the pair of R₂₅₁ and R₂₅₂ and the pair of R₂₅₂ and R₂₅₃ donot form a ring simultaneously; the pair of R₂₅₄ and R₂₅₅ and the pairof R₂₅₅ and R₂₅₆ do not form a ring simultaneously; the pair of R₂₅₅ andR₂₅₆ and the pair of R₂₅₆ and R₂₅₇ do not form a ring simultaneously;the pair of R₂₅₈ and R₂₅₉ and the pair of R₂₅₉ and R₂₆₀ do not form aring simultaneously; and the pair of R₂₅₉ and R₂₆₀ and the pair of R₂₆₀and R₂₆₁ do not form a ring simultaneously;

When two or more rings are formed by R₂₅₁ to R₂₆₁, the rings may be thesame or different;

R₂₅₁ to R₂₆₁ that do not form the substituted or unsubstituted,saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms, or-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and-   R₉₀₁ to R₉₀₇ are as defined in the formula (1).

In the formula (25), R_(n) and R_(n+1) (n is an integer selected from251, 252, 254 to 256 and 258 to 260) bond with each other to form asubstituted or unsubstituted, saturated or unsaturated ring togetherwith two ring carbon atoms to which R_(n) and R_(n+1) bond with. Thering is preferably configured with atoms selected from C atom, O atom, Satom and N atom, and the number of atoms is preferably 3 to 7, morepreferably 5 or 6.

The number of the above-described ring structures in the compoundrepresented by the formula (25) is, for example, 2, 3 or 4. Two or morering structures may exist in the same benzene ring of the main skeletonin the formula (25), or may exist in different benzene rings. Forexample, the compound has three ring structures, one ring structure mayexist in each of the three benzene rings in the formula (25).

As the above-mentioned ring structure in the compound represented by theformula (25), structures represented by the following formulas (251) to(260) can be given, for example.

wherein in the formulas (251) to (257),

each of *1 and *2, *3 and *4, *5 and *6, *7 and * 8, *9 and *10, *11 and*12, and *13 and *14 represents two ring carbon atoms to which R_(n) andR_(n+1) bond, and R_(n) may bond to either one of the two ring carbonatoms of *1 and * 2, *3 and *4, *5 and *6, *7 and *8, *9 and *10, *11and *12, and *13 and *14;

X₂₅₀₁ is C(R₂₅₁₂) (R₂₅₁₃), NR₂₅₁₄, O or S;

One or more pairs of two or more adjacent groups of R₂₅₀₁ to R₂₅₀₆ andR₂₅₁₂ to R₂₅₁₃ are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring, or do not form asubstituted or unsubstituted saturated or unsaturated ring; and

R₂₅₀₁ to R₂₅₁₄ that do not form a substituted or unsubstituted saturatedor unsaturated ring are the same as R₂₅₁ to R₂₆₁.

wherein in the formulas (258) to (260),

each of *1 and *2, and *3 and *4 represents two ring carbon atoms towhich R_(n) and R_(n+1) bond, and R_(n) may bond to either one of thetwo ring carbon atoms of *1 and *2 or *3 and *4;

X₂₅₀₁ is C(R₂₅₁₂) (R₂₅₁₃), NR₂₅₁₄, O or S;

One or more pairs of two or more adjacent groups of R₂₅₁₅ to R₂₅₂₅ bondto each other to form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstitutedsaturated or unsaturated ring; and

R₂₅₁₅ to R₂₅₂₁ and R₂₅₂₂ to R₂₅₂₅that do not form a substituted orunsubstituted saturated or unsaturated ring are the same as R₂₅₁ toR₂₆₁.

In the formula (25), it is preferable that at least one of R₂₅₂, R₂₅₄,R₂₅₅, R₂₆₀ and R₂₆₁ (preferably at least one of R₂₅₂, R₂₅₅, and R₂₆₀,more preferably R₂₅₂) is a group which does not form a ring.

-   (i) Substituent in the case where the ring structure formed by R_(n)    and R_(n+1) has a substituent in the formula (25),-   (ii) R₂₅₁ to R₂₆₁ that do not form a ring structure in the formula    (25), and-   (iii) R₂₅₀₁ to R₂₅₁₄ and R₂₅₁₅ to R₂₅₂₅ in the formulas (251)    to (260) are preferably independently-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —N(R₉₀₆) (R₉₀₇),-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms,-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms, or-   a group selected from the following groups.

wherein in the formulas (261) to (264),

R_(d)s are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

X is C(R₉₀₁)(R₉₀₂), NR₉₀₃, O, or S;

R₉₀₁ to R₉₀₇ are as defined in the formula (1); and

p1 is independently an integer of 0 to 5, p2 is independently an integerof 0 to 4, p3 is an integer of 0 to 3, and p4 is an integer of 0 to 7.

In one embodiment, the compound represented by the formula (25) isrepresented by the following formulas (25-1) (25-6).

wherein in the formulas (25-1) to (25-6), ring d to ring i areindependently a substituted or unsubstituted, saturated or unsaturatedring; and R₂₅₁to R₂₆₁ are the same as defined in the formula (25).

In one embodiment, the compound represented by the formula (25) isrepresented by the following formulas (25-7) to (25-12).

wherein in the formulas (25-7) to (25-12), ring d to ring f, ring k, andring j are independently a substituted or unsubstituted, saturated orunsaturated ring; and 8253 to R₂₆₁ are the same as defined in theformula (25).

In one embodiment, the compound represented by the formula (25) isrepresented by the following formulas (25-13) to (25-21).

wherein in the formulas (25-13) to (25-21), ring d to ring k areindependently a substituted or unsubstituted, saturated or unsaturatedring; and R₂₅₁ to R₂₆₁ are the same as defined in the formula (25).

As a substituent in the case where the ring g or ring h further has asubstituent, a substituted or unsubstituted alkyl group having 1 to 50carbon atoms, a substituted or unsubstituted aryl group having 6 to 50ring carbon atoms, or a group represented by the formula (261), (263) or(264) can be given for example.

In one embodiment, the compound represented by the formula (25) isrepresented by one of the following formulas (25-22) to (25-25).

wherein in the formulas (25-22) to (25-25), X₂₅₀ is C(R₉₀₁)(R₉₀₂),NR₉₀₃, O or S; R₂₅₁ to R₂₆₁, and R₂₇₁ to R₂₇₈ are the same as R₂₅₁ toR₂₆₁ in the formula (25); and R₉₀₁ to R₉₀₃ are as defined in the formula(1),

In one embodiment, the compound represented by the formula (25) isrepresented by the following formula (25-26).

wherein in the formula (25-26), X₂₅₀ is C(R₉₀₁)(R₉₀₂), NR₉₀₃, O or S;R₂₅₃, R₂₅₄, R₂₅₇, R₂₅₃, R₂₆₁, and R₂₇₁ to R₂₈₂ are the same as R₂₅₁ toR₂₆₁ in the formula (25); and R₉₀₁ to R₉₀₃ are as defined in the formula(1).

As the compound represented by the formula (21), the following compoundscan be shown for example. In the following example compounds, Merepresents methyl group.

(Compound Represented by Formula (31))

The compound represented by the formula (31) is explained below.

The compound represented by formula (31) is a compound corresponding tothe compound represented by the formula (21-3).

wherein in the formula (31),

one or more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ andR₃₁₁ to R₃₁₇ form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ that do not form the substituted orunsubstituted, saturated or unsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₃₂₁ and R₃₂₂ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

Example of “One pair of two or more adjacent groups of R₃₀₁ to R₃₀₇ andR₃₁₁ to R₃₁₇” is pairs of R₃₀₁ and R₃₀₂, R₃₀₂ and R₃₀₃ R₃₀₃ and R₃₀₄,R₃₀₅ and R₃₀₆, R₃₀₆ and R₃₀₇, and R₃₀₁, R₃₀₂ and R₃₀₃, and the like.

In one embodiment, at least one of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇,preferably two of R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ is a group representedby —N(R₉₀₆)(R₉₀₇).

In one embodiment, R₃₀₁ to R₃₀₇ and R₃₁₁ to R₃₁₇ are independently ahydrogen atom, a substituted or unsubstituted aryl group having 6 to 50ring carbon atoms, or a substituted or unsubstituted monovalentheterocyclic group having 5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is acompound represented by the following formula (32).

wherein in the formula (32),

one or more pairs of two or more adjacent groups of R₃₃₁ to R₃₃₄ andR₃₄₁ to R₃₄₄ form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstitutedsaturated or unsaturated ring;

R₃₃₁ to 8334 and R₃₄₁ to R₃₄₄ that do not form the substituted orunsubstituted, saturated or unsaturated ring and R₃₅₁ and R₃₅₂ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₃₆₁ to R₃₆₄ are independently

-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is acompound represented by the formula (33).

wherein in the formula (33), R₃₅₁, R₃₅₂, and R₃₆₁ to R₃₆₄ are as definedin the formula (32).

In one embodiment, the compound represented by the formula (31) is acompound represented by the formula (34) or (35).

wherein in the formulas (34) and (35),

R₃₆₁ to R₃₆₄ are as defined in the formula (32);

one or more pairs of two or more adjacent groups of R₃₇₁ to R₃₇₇ andR₃₈₀ to R₃₈₆ form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstitutedsaturated or unsaturated ring;

R₃₇₁ to R₃₇₇ and R₃₈₀ to R₃₃₅ that do not form the substituted orunsubstituted, saturated or unsaturated ring and R₃₈₇ are independently

-   a hydrogen atom,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

two R₃₈₇s may be the same with or different from each other.

In one embodiment, the compound represented by the formula (31) is acompound represented by the formula (34-2) or (35-2).

wherein in the formulas (34-2) and (35-2), R₃₆₁ to R₃₆₄, R₃₇₅ to R₃₇₇and R₃₈₄ to R₃₈₇ are as defined in the formulas (34) and (35),

In one embodiment, R₃₆₁ to R₃₆₄ in the formulas (32), (33), (34), (35),(34-2) and (35-2) are independently a substituted or unsubstituted arylgroup having 6 to 50 ring carbon atoms (preferably a substituted orunsubstituted phenyl group).

In one embodiment, R₃₂₁ and R₃₂₂ in the formula (31) and R₃₅₁, R₃₅₂ andR₃₈₇ in the formulas (32), (33), (34), (35), (34-2) and (35-2) areindependently a hydrogen atom or a substituted or unsubstituted arylgroup having 6 to 50 ring carbon atoms (preferably a substituted orunsubstituted phenyl group).

In one embodiment, the compound represented by the formula (31) is oneor more compounds selected from the group consisting of the followingformulas (32-11), (34-11) and (35-11).

wherein in the formulas (32-11), (34-11) and (35-11),

one or more pairs of two or more adjacent groups of R₃₃₀₁ to R₃₃₀₇ andR₃₃₁₁ to R₃₃₁₇ form a substituted or unsubstituted, saturated orunsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

R₃₃₀₁ to R₃₃₀₇ and R₃₃₁₁ to R₃₃₁₇ that do not form the substituted orunsubstituted, saturated or unsaturated ring, and R₃₃₃₁ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted aryl group having 6 to 20 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 20 ring atoms;

two R₃₃₃₁s may be the same with or different from each other; and

R₃₃₂₁ to R₃₃₂₄ are independently

-   a substituted or unsubstituted aryl group having 6 to 20 ring carbon    atoms, or

a substituted or unsubstituted monovalent heterocyclic group having 5 to20 ring atoms.

In one embodiment, the one or more compounds selected from the groupconsisting of the formulas (32-11), (34-11) and (35-11) is one or morecompounds selected from a group consisting of the following formulas(32-12), (34-12) and (35-12).

wherein in the formulas (32-12), (34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ andR₃₃₃₁ are as defined in the formulas (32-11), (34-11) and (35-11).

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted orunsubstituted phenyl group.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), two R3331s are independently a hydrogen atom.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), the substituent in the case of “substituted orunsubstituted” is selected from the group consisting of an alkyl grouphaving 1 to 20 carbon atoms, an aryl group having 6 to 20 ring carbonatoms, and a monovalent heterocyclic group having 5 to 20 ring atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), the substituent in the case of “substituted orunsubstituted” is an alkyl group having 1 to 5 carbon atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted orunsubstituted phenyl group, and two R₃₃₃₁s are independently a hydrogenatom.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted orunsubstituted phenyl group, two R₃₃₃₁s are independently a hydrogenatom, and the substituent in the case of “substituted or unsubstituted”is selected from the group consisting of an alkyl group having 1 to 20carbon atoms, an aryl group having 6 to 20 ring carbon atoms, and amonovalent heterocyclic group having 5 to 20 ring atoms.

In one embodiment, in the formulas (32-11), (34-11), (35-11), (32-12),(34-12) and (35-12), R₃₃₂₁ to R₃₃₂₄ are independently a substituted orunsubstituted phenyl group, two R₃₃₃₁s are independently a hydrogenatom, and the substituent in the case of “substituted or unsubstituted”is an alkyl group having 1 to 5 carbon atoms.

In one embodiment, in the compound represented by the formula (31), oneor more pairs of two or more adjacent groups of R₃₀₁ to R₃₀₇ and R₃₁₁ toR₃₁₇ form a substituted or unsubstituted, saturated or unsaturated ring.

In one embodiment, the compound represented by the formula (31) is oneor more compounds selected from the group consisting of the followingformulas (36-1) to (36-6).

wherein in the formulas (36-1) to (36-6),

one or more pairs of two or more adjacent groups of R₃₆₀₅ to R₃₅₀₇,R₃₆₁₅ to R₃₆₁₇ and R₃₆₃₁ bond with each other to form a substituted orunsubstituted, saturated or unsaturated ring or do not form the ring;

one or more pairs of two or more adjacent groups of R₃₆₀₁ to R₃₆₀₄,R₃₆₁₁ to R₃₆₁₄ and R₃₆₂₁ to R₃₆₂₈ bond with each other to form asubstituted or unsubstituted, saturated or unsaturated ring or do notform the ring;

R₃₆₀₁ to R₃₆₀₇, R₃₆₁₁ to R₃₆₁₇, R₃₆₂₁ to R₃₆₂₈ and R₃₆₃₁ that do notform the ring are independently

-   a hydrogen atom, a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

when two or more of R₉₀₁ to R₉₀₇ exist, two or more of R₉₀₁ to R₉₀₇ maybe the same with or different from each other;

X₁ is selected from O, S and NI(R₃₆₄₁), and two X₁s may be the same withor different from each other;

R₃₆₄₁ and one or more groups selected from R₃₆₀₁ to R₃₆₀₄, R₃₆₁₁ toR₃₆₁₄, R₃₆₂₄ and R₃₆₂₈ bond with each other to form a substituted orunsubstituted, saturated or unsaturated ring or do not form the ring;and

R₃₆₄₁ that do not form the ring is a hydrogen atom,

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

In one embodiment, the compound represented by the formula (31) is acompound represented by the formula (36-1) or (36-2), In one embodiment,the compound represented by the formula (31) is a compound representedby the formula (36-1).

In one embodiment, in the compound represented by the formulas (36-1) to(36-6), two R₃₆₃₁s are phenyl groups.

In one embodiment, in the compound represented by the formulas (36-1) to(36-6), X₁ is N(R₃₆₄₁).

In one embodiment, in the compound represented by the formulas (36-1) to(36-6), R₃₆₄₁ is a substituted or unsubstituted awl group having 6 to 50ring carbon atoms.

In one embodiment, the compound represented by the formula (31) is acompound represented by the following formula (36-1-1).

wherein in the formula (36-11),

one or more pairs of two or more adjacent groups of R₃₀₀₁, R₃₀₀₂, R₃₀₀₅to R₃₀₀₇, R₃₀₁₀, R₃₀₁₁, R₃₀₁₄ to R₃₀₁₆ and R₃₀₃₁ to R₃₀₃₄ bond with eachother to form a substituted or unsubstituted, saturated or unsaturatedring or do not form the ring;

X_(a)s are independently selected from O, S and N(R₃₀₃₅);

R₃₀₃₅ and R₃₀₃₁ bond with each other to form a substituted orunsubstituted, saturated or unsaturated ring or do not form the ring;and

R₃₀₀₁, R₃₀₀₂, R₃₀₀₅ to R₃₀₀₇, R₃₀₁₀, R₃₀₁₁, R₃₀₁₄ to R₃₀₁₆ and R₃₀₃₁ toR₃₀₃₅ that do not form the ring and R₃₀₂₁ and R₃₀₂₂ are independently

-   a hydrogen atom,-   a substituted or unsubstituted awl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

In one embodiment, a substituent in the case of “substituted orunsubstituted ” in the formulas (31) to (35), (34-2), (35-2), (32-11),(34-11), (35-11), (32-12), (34-12), (35-12), (36-1) to (36-6) and(36-1-1) is

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

As the compound represented by the formula (31), the following compoundscan be given for example. In the following example compounds, Merepresents methyl group.

(Compound Represented by Formula (41))

The compound represented by the formula (41) is explained below.

wherein, in the formula (41),

a ring, b ring and c ring are independently

a substituted or unsubstituted aromatic hydrocarbon ring having 6 to 50ring carbon atoms, or a substituted or unsubstituted heterocyclic ringhaving 5 to 50 ring atoms;

R₄₀₁ and R₄₀₂ are independently bonded to the a ring, the b ring or thec ring to form a substituted or unsubstituted heterocyclic ring or donot form a substituted or unsubstituted heterocyclic ring;

R₄₀₁ and R₄₀₂ that do not form the substituted or unsubstitutedheterocyclic ring are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

The a ring, b ring and c ring are rings (a substituted or unsubstitutedaromatic hydrocarbon ring having 6 to 50 ring carbon atoms or asubstituted or unsubstituted heterocyclic ring having 5 to 50 ringatoms) fuse to the fused bicyclic structure composed of B atom and two Natoms in the center of the formula (41).

The “aromatic hydrocarbon ring” of the a ring, the b ring and the c ringhas the same structure as the compound obtained by introducing ahydrogen atom into the “aryl group” described above. The “aromatichydrocarbon ring” of the a ring contains three carbon atoms in the fusedbicyclic structure in the center of the formula (41) as ring atoms. The“aromatic hydrocarbon ring” of the b ring and the c ring contain twocarbon atoms in the fused bicyclic structure in the center of theformula (41) as ring atoms. As examples of “substituted or unsubstitutedaromatic hydrocarbon ring having 6 to 50 ring carbon atoms”, compoundsin which a hydrogen atom is introduced into the “aryl group” describedin the group G1 and the like can be given.

The “heterocyclic ring” of the a ring, the b ring and the c ring has thesame structure as the compound obtained by introducing a hydrogen atominto the “heterocyclic group” described above. The “heterocyclic ring”of the a ring contains three carbon atoms in the fused bicyclicstructure in the center of the formula (41) as ring atoms. The“heterocyclic ring” of the b ring and the c ring contain two carbonatoms in the fused bicyclic structure in the center of the formula (41)as ring atoms. As examples of “substituted or unsubstituted heterocyclicring having 5 to 50 ring atoms”, compounds in which a hydrogen atom isintroduced into the “heterocyclic group” described in the group G2.

R₄₀₁ and R₄₀₂ may be independently bonded to the a ring, the b ring orthe c ring to form a substituted or unsubstituted heterocyclic ring.This heterocyclic ring contains the nitrogen atom in the fused bicyclicstructure in the center of the formula (41). This heterocyclic ring maycontain a heteroatom other than the nitrogen atom. “R₄₀₁ and R₄₀₂ arebonded to the a ring, the b ring or the c ring” means, specifically, anatom forming the a ring, the b ring or the c ring is bonded to an atomforming R₄₀₁ and R₄₀₂. For example, it is possible that R₄₀₁ is bondedto the a ring to form a nitrogen-containing heterocyclic ring having atwo-ring fused structure (or three or more rings fused structure) inwhich a ring containing R₄₀₁ and the a ring are fused.

The same applies to the case where R₄₀₁ is bonded to the b ring, R₄₀₂ isbonded to the a ring, and R₄₀₂ is bonded to the c ring.

In one embodiment, the a ring, the b ring and the e ring in the formula(41) are independently a substituted or unsubstituted aromatichydrocarbon ring having 6 to 50 ring carbon atoms.

In one embodiment, the a ring, the b ring and the c ring in the formula(41) are independently a substituted or unsubstituted benzene ring or asubstituted or unsubstituted naphthalene ring.

In one embodiment, R₄₀₁ and R₄₀₂ in the formula (41) are independently asubstituted or unsubstituted aryl group having 6 to 50 ring carbonatoms, or a substituted or unsubstituted monovalent heterocyclic grouphaving 5 to 50 ring atoms, and preferably a substituted or unsubstitutedaryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (41) is acompound represented by the following formula (42).

wherein in the formula (42),

R_(401A) is bonded with one or more groups selected from R₄₁₁ or R₄₂₁ toform a substituted or unsubstituted heterocyclic ring, or does not forma substituted or unsubstituted heterocyclic ring; R_(402A) is bondedwith one or more group selected from R₄₁₃ or R₄₁₄ to form a substitutedor unsubstituted heterocyclic ring, or does not form a substituted orunsubstituted heterocyclic ring;

R_(401A) and R_(402A) that do not form a substituted or unsubstitutedheterocyclic ring are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

One or more pairs of two or more adjacent groups of R₄₁₁ to R₄₂₁ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

R₄₁₁ to R₄₂₁ that do not form the substituted or unsubstitutedheterocyclic ring or the substituted or unsubstituted, saturated orunsaturated ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

R_(401A) and R_(402A) in the formula (42) correspond to R₄₀₁ and R₄₄₂ inthe formula (41).

R_(401A) and R₄₁₁ may be bonded with each other to form anitrogen-containing heterocyclic ring having two-ring fused structure(or three or more rings fused structure) which is a fused ring of a ringcontaining R_(401A) and R₄₁₁ and the benzene ring of the a ring, forexample. As examples of the nitrogen-containing heterocyclic ring,compounds correspond to nitrogen-containing heterocyclic group havingtwo or more ring fused structure in the group G2 can be given. The sameapplies to the cases where R_(401A) and R₄₁₂ are bonded, R_(402A) andR₄₁₃ are bonded and R_(402A) and R₄₁₄ are bonded.

One or more pairs of two or more adjacent groups of R₄₁₁ to R₄₂₁ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring. For example, R₄₁₁ and R₄₁₂ are bonded to form abenzene ring, an indole ring, a pyrrole ring, a benzofuran ring, abenzothiophene ring or the like which fuses to the six-membered ring towhich R₄₁₁ and R₄₁₂ bond, and the formed fused ring is a naphthalenering, a carbazole ring, an indole ring, a dibenzofuran ring or adibenzothiophene ring.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ringare independently a hydrogen atom, a substituted or unsubstituted alkylgroup having 1 to 50 carbon atoms, a substituted or unsubstituted arylgroup having 6 to 50 ring carbon atoms, or a substituted orunsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ringare independently a hydrogen atom, a substituted or unsubstituted arylgroup having 6 to 50 ring carbon atoms, or a substituted orunsubstituted monovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ringare independently a hydrogen atom or a substituted or unsubstitutedalkyl group having 1 to 50 carbon atoms.

In one embodiment, R₄₁₁ to R₄₂₁ that do not contribute to form a ringare independently a hydrogen atom, a substituted or unsubstituted alkylgroup having 1 to 50 carbon atoms, and at least one of R₄₁₁ to R₄₂₁ is asubstituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, the compound represented by the formula (42) is acompound represented by the following formula (43).

wherein in the formula (43),

R₄₃₁ is bonded with R₄₄₈ to form a substituted or unsubstitutedheterocyclic ring, or does not form a substituted or unsubstitutedheterocyclic ring; R₄₃₃ is bonded with R₄₄₇ to form a substituted orunsubstituted heterocyclic ring, or does not form a substituted orunsubstituted heterocyclic ring; R₄₃₄ is bonded with R₄₅₁ to form asubstituted or unsubstituted heterocyclic ring, or does not form asubstituted or unsubstituted heterocyclic ring; R₄₄₁ is bonded with R₄₄₂to form a substituted or unsubstituted heterocyclic ring, or does notform a substituted or unsubstituted heterocyclic ring;

One or more pairs of two or more adjacent groups of R₄₃₁ to R₄₅₁ arebonded with each other to form a substituted or unsubstituted, saturatedor unsaturated ring, or do not form a substituted or unsubstituted,saturated or unsaturated ring;

R₄₃₁ to R₄₅₁ that do not form a substituted or unsubstitutedheterocyclic ring are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

R₄₃₁ may bond to R₄₄₆ to form a substituted or unsubstitutedheterocyclic ring. For example, R₄₃₁ may bonds with R₄₄₆ to form anitrogen-containing heterocyclic ring with three or more fused rings ofthe benzene ring to which R₄₆ bond, a nitrogen-containing ring and thebenzene ring of the a ring. As examples of the nitrogen-containingheterocyclic ring, compounds correspond to nitrogen-containingheterocyclic group having three or more ring fused structure in thegroup G2 can be given. The same applies to the cases where R₄₃₃ and R₄₄₇are bonded, R₄₃₄ and R₄₅₁ are bonded, and R₄₄₁ and R₄₄₂ are bonded.

In one embodiment, R₄₃₁ to R₄₅₁ that do not contribute to form a ringare independently, a hydrogen atom, a substituted or unsubstituted alkylgroup having 1 to 50 carbon atoms, a substituted or unsubstituted arylgroup having 6 to 50 carbon atoms, or a substituted or unsubstitutedmonovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₃₁ to R₄₅₁ that do not contribute to form a ringare independently, a hydrogen atom, a substituted or unsubstituted arylgroup having 6 to 50 carbon atoms, or a substituted or unsubstitutedmonovalent heterocyclic group having 5 to 50 ring atoms.

In one embodiment, R₄₃₁ to R₄₅₁ that do not contribute to form a ringare independently a hydrogen atom or a substituted or unsubstitutedalkyl group having 1 to 50 carbon atoms.

In one embodiment, R₄₃₁ to R₄₅₁ that do not contribute to form a ringare independently a hydrogen atom, a substituted or unsubstituted alkylgroup having 1 to 50 carbon atoms, and at least one of R₄₃₁ to R₄₅₁ is asubstituted or unsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, the compound represented by the formula (43) is acompound represented by the following formula (43A),

wherein in the formula (43A),

R₄₆₁ is

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms, or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms; and

R₄₆₂ to R₄₆₅ are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms, or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms,

In one embodiment, R₄₆₁ to R₄₆₅ are independently a substituted orunsubstituted alkyl group having 1 to 50 carbon atoms or a substitutedor unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₄₈₁ and R₄₆₅ are independently a substituted orunsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, the compound represented by the formula (43) is acompound represented by the following formula (43B).

wherein in the formula (43B),

R₄₇₁ and R₄₇₂ are independently,

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —N(R₉₀₆) (R₈₀₇), or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms,

R₄₇₃ to R₄₇₅ are independently,

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —N(R₉₀₆) (R₉₀₇), or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms: and

R₉₀₆ and 8907 are as defined in the formula (1).

In one embodiment, the compound represented by the formula (43) is thecompound represented by the following formula (43B′).

wherein in the formula (43B′), R₄₇₂ to R₄₇₅ are as defined in theformula (43B).

In one embodiment, at least one of R₄₇₁ to R₄₇₅ is

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —N(R₉₀₆) (R₉₀₇), or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms.

In one embodiment.

R₄₇₂ is

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   —N(R₉₀₆) (R₉₀₇), or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms; and

R₄₇₁ and R₄₇₃ to R₄₇₅ are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   —N(R₉₀₆) (R₉₃₇), or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms.

In one embodiment, the compound represented by the formula (43) is acompound represented by the formula (43C).

wherein in the formula (43C),

R₄₈₁ and R₄₆₂ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms, or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms; and

R₄₆₃ to R₄₈₆ are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms, or-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms,

In one embodiment, the compound represented by the formula (43) is thecompound represented by the following formula (43C′).

wherein in the formula (43C′), R₄₈₃ to R₄₈₆ are as defined in theformula (43C).

In one embodiment, R₄₈₁ to R₄₈₆ are independently a substituted orunsubstituted alkyl group having 1 to 50 carbon atoms or a substitutedor unsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₄₈₁ to R₄₈₆ are independently a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, the compound represented by the formula (43) is acompound represented by the following formula (43D):

wherein in the formula (43D),

R₄₆₁₁ is a hydrogen atom, an unsubstituted alkyl group including 1 to 6carbon atoms, an unsubstituted cycloalkyl group including 3 to 10 ringcarbon atoms, —Si(R₉₁₁)(R₉₁₂)(R₉₁₃), or —N(R₉₁₄)(R₉₁₅);

R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including1 to 6 carbon atoms, an unsubstituted cycloalkyl group including 3 to 10ring carbon atoms, or —Si(R₉₁₁)(R₉₁₂)(R₉₁₃);

R₉₁₁ to R₉₁₃ are independently an unsubstituted alkyl group including 1to 6 carbon atoms or an unsubstituted aryl group including 6 to 18 ringcarbon atoms;

R₉₁₄ to R₉₁₅ are independently an unsubstituted aryl group including 6to 18 ring carbon atoms.

In one embodiment, in the formula (43D), R₄₆₁₁ is a hydrogen atom, anunsubstituted alkyl group including 1 to 6 carbon atoms, or—N(R₉₁₄)(R₉₁₅).

In one embodiment, in the formula (43D), R₄₆₁₂ to R₄₆₁₅ areindependently an unsubstituted alkyl group including 1 to 6 carbonatoms, or an unsubstituted cycloalkyl group including 3 to 10 ringcarbon atoms.

In one embodiment, in the formula (43D), R₄₆₁₁ is —N(R₉₁₄)(R₉₁₅), andR₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including1 to 6 carbon atoms.

In one embodiment, in the formula (43D), R₄₆₁₁ is an unsubstituted alkylgroup including 1 to 6 carbon atoms, and R₄₆₁₂ to R₄₆₁₅ areindependently an unsubstituted alkyl group including 1 to 6 carbonatoms.

In one embodiment, in the formula (43D), R₄₆₁₁ is a hydrogen atom, andR₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl group including1 to 6 carbon atoms, or an unsubstituted cycloalkyl group including 3 to10 ring carbon atoms.

In one embodiment, in the formula (43D), at least one of the hydrogenatoms included in one or more selected from the group consisting of R₉₁₄and R₉₁₅ is a deuterium atom.

The compound represented by the formula (41) can be synthesized by thefollowing method: An intermediate is obtained by bonding the a ring, theb ring and the c ring with linking groups (a group containing N—R₁ and agroup containing N—R₂) (first reaction), and a final compound isobtained by bonding the a ring, the b ring and the c ring with a linkinggroup (a group containing B) (second reaction). In the first reaction,an amination reaction such as Buchwald-Hartwig reaction can be applied.In the second reaction, tandem hetero-Friedel-Crafts reaction or thelike can be applied.

Examples of the compound represented by the formula (41) are describedbelow. They are just exemplified compounds and the compound representedby the formula (41) is not limited to the following examples. In thefollowing example compounds, Me represents methyl group, and tBurepresents tert-butyl group.

(Compound Represented by Formula (51))

The compound represented by the formula (51) is explained below,

wherein, in the formula (51),

r ring is a ring represented by the formula (52) or formula (53) whichis fused to an adjacent ring at an arbitrary position;

q ring and s ring are independently a ring represented by the formula(54) which is fused to an adjacent ring at an arbitrary position;

p ring and t ring are independently a ring represented by the formula(55) or the formula (56) which is fused to an adjacent ring at anarbitrary position;

when plural R₅₀₁s exist, adjacent plural R₅₀₁s are bonded with eachother to form a substituted or unsubstituted, saturated or unsaturatedring, or do not form a substituted or unsubstituted, saturated orunsaturated ring;

X₅₀₁ is an oxygen atom, a sulfur atom, or NR₅₀₂;

R₅₀₁ and R₅₀₂ that do not form the substituted or unsubstitutedsaturated or unsaturated ring are

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

Ar₅₀₁ and Ar₅₀₂ are independently

-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

L₅₀₁ is

-   a substituted or unsubstituted alkylene group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenylene group having 2 to 50    carbon atoms,-   a substituted or unsubstituted alkynylene group having 2 to 50    carbon atoms,-   a substituted or unsubstituted cycloalkylene group having 3 to 50    ring carbon atoms,-   a substituted or unsubstituted arylene group having 6 to 50 ring    carbon atoms, or-   a substituted or unsubstituted divalent heterocyclic group having 5    to 50 ring atoms;

m1 is independently an integer of 0 to 2, m2 is independently an integerof 0 to 4, m3s are independently an integer of 0 to 3, and m4s areindependently an integer of 0 to 5; when plural R₅₀₁s exist, the pluralR₅₀₁s may be the same or different;

In the formula (51), each of the p ring to the t ring is fused to anadjacent ring by sharing two carbon atoms. The position and direction offusing are not limited, and condensation is possible at any position anddirection.

In one embodiment, in the formula (52) or (53) of the r ring, R₅₀₁ is ahydrogen atom.

In one embodiment, the compound represented by the formula (51) isrepresented by any one of the following formulas (51-1) to (51-6).

wherein in the formulas (51-1) to (51-6), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂. Lot,m1 and m3 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) isrepresented by any one of the following formulas (51-11) to (51-13).

wherein in the formulas (51-11) to (51-13), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂,L₅₀₁, m1, m3 and m4 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) isrepresented by any one of the following formulas (51-21) to (51-25),

wherein in the formulas (51-21) to (51-25), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂,L₅₀₁, m1 and m4 are as defined in the formula (51).

In one embodiment, the compound represented by the formula (51) isrepresented by any one of the following formulas (51-31) to (51-33).

wherein in the formulas (51-31) to (51-33), R₅₀₁, X₅₀₁, Ar₅₀₁, Ar₅₀₂,L₅₀₁, m2 to m4 are as defined in the formula (51),

In one embodiment, Ar₅₀₁ and Ar₅₀₂ are independently a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, one of Ar₅₀₁ and Ar₅₀₂ is a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms and the otheris a substituted or unsubstituted monovalent heterocyclic ring having 5to 50 ring atoms.

As examples of the compound represented by the formula (51), thefollowing compounds can be given, for example. In the following examplecompounds, Me represents methyl group.

(Compound Represented by Formula (61))

The compound represented by the formula (61) is explained below.

wherein, in the formula (61),

at least one pair of R₆₀₁ and R₆₀₂, R₆₀₂ and R₆₀₃, and R₆₀₃ and R₆₀₄ arebonded with each other to form a divalent group represented by theformula (62);

at least one pair of R₆₀₅ and R₆₀₆, R₆₀₆ and R₆₀₇, and R₆₀₇ and R₆₀₈ arebonded with each other to form a divalent group represented by formula(63);

at least one of R₆₀₁ to R₆₀₄ that does not form the divalent grouprepresented by the formula (62), and R₆₁₁ to R₆₁₄ is a monovalent grouprepresented by the following formula (64);

at least one of R₆₀₅ to R₆₀₈ that do not form the divalent grouprepresented by the formula (63), and R₆₂₁ to R₆₂₄ is a monovalent grouprepresented by the following formula (64);

X₆₀₁ is an oxygen atom, a sulfur atom, or NR₆₀₉;

R₆₀₁ to R₆₀₈ that do not form the divalent group represented by theformulas (62) and (63) and that is not the monovalent group representedby the formula (64), R₆₁₁ to R₆₁₄ and R₆₂₁ to R₆₂₄ that are not themonovalent group represented by the formula (64), and R₆₀₉ areindependently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or a substituted or unsubstituted monovalent heterocyclic    group having 5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

wherein, in the formula (64), Ar₆₀₁ and Arson are independently asubstituted or unsubstituted aryl group having 6 to 50 ring carbonatoms, or a substituted or unsubstituted monovalent heterocyclic grouphaving 5 to 50 ring atoms;

L₆₀₁ to L₆₀₃ are independently

-   a single bonded,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms,-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms, or-   a divalent linking group formed by bonding 2 to 4 above mentioned    groups;

In the formula (61), positions at which the divalent group representedby the formula (62) and the divalent group represented by the formula(63) are formed are not limited, and said groups can be formed atpossible positions in R₆₀₁ to R₆₀₈.

In one embodiment, the compound represented by the formula (61) isrepresented by any one of the following formulas (61-1) to (61-6).

wherein in the formulas (61-1) to (61-6), X₆₀₁ is as defined in theformula (61);

at least two of R₆₀₁ to R₆₂₄ are monovalent groups represented by theformula (64);

R₆₀₁ to R₆₂₄ that are not monovalent groups represented by the formula(64) are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

In one embodiment, the compound represented by the formula (61) isrepresented by any one of the following formulas (61-7) to (61-18).

wherein in the formulas (61-7) to (61-18), X₆₀₁ is as defined in theformula (61); * is a single bond bonding to the monovalent grouprepresented by the formula (64); and R₆₀₁ to R₆₂₄ are the same as R₆₀₁to R₆₂₄ that are not monovalent groups represented by the formula (64).

R₆₀₁ to R₆₀₈ which do not form the divalent group represented by theformula (62) and (63) and are not monovalent groups represented by theformula (64), and R₆₁₁ to R₆₁₄ and R₆₂₁ to R₆₂₄ which are not monovalentgroups represented by the formula (64) are preferably independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms.

The monovalent group represented by the formula (64) is preferablyrepresented by the following formulas (65) or (66).

wherein in the formula (65), R₆₃₁ to R₆₄₀ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).

wherein in the formula (66), Ar₆₀₁, L₆₀₁ and L₆₀₃ are as defined in theformula (64); and HAr₆₀₁ is a structure represented by the followingformula (67);

wherein in the formula (67) X₆₀₂ is an oxygen atom or a sulfur atom;

any one of R₆₄₁ to R₆₄₈ is a single bond bonding to L₆₀₃;

R₆₄₁ to R₆₄₈ which are not single bonds are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms; and

R₉₀₁ to R₉₀₇ are as defined in the formula (1).)

As specific example of the compound represented by the formula (61), inaddition to the compounds described in WO2014/104144, the followingcompounds can be given, for example. In the following example compounds,Me represents methyl group.

(Compound represented by formula (71))

The compound represented by the formula (71) is explained below.

wherein, in the formula (71),

A₇₀₁ ring and A₇₀₂ ring are independently

-   a substituted or unsubstituted aromatic hydrocarbon ring having 6 to    50 ring carbon atoms, or-   a substituted or unsubstituted heterocyclic ring having 5 to 50 ring    atoms;

One or more rings selected from the group consisting of A₇₀₁ ring andA₇₀₂ ring are bonded to the bond * of the structure represented by thefollowing formula (72);

wherein, in the formula (72),

A₇₀₃ rings are independently

-   a substituted or unsubstituted aromatic hydrocarbon ring having 6 to    50 ring carbon atoms, or-   a substituted or unsubstituted heterocyclic ring having 5 to 50 ring    atoms;

X₇₀₁ is N R₇₀₃, C(R₇₀₄)(R₇₀₅), Si(R₇₀₆) (R₇₀₇), Ge(R₇₀₈) (R₇₀₉), O, S orSe;

R₇₀₁ and R₇₀₂ are bonded with each other to form a substituted orunsubstituted, saturated or unsaturated ring or do not form asubstituted or unsubstituted saturated or unsaturated ring;

R₇₀₁ and R₇₀₂ that do not form the substituted or unsubstituted,saturated or unsaturated ring, and R₇₀₃ to R₇₀₉ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

One or more selected from the group consisting of A₇₀₁ ring and A₇₀₂ring is bonded to * in the structure represented by the formula (72).That is, in one embodiment, the ring carbon atom of the aromatichydrocarbon ring or the ring atom of the heterocyclic ring of A₇₀₁ ringis bonded to * in the structure represented by the formula (72). In oneembodiment, the ring carbon atom of the aromatic hydrocarbon ring or thering atom of the heterocyclic ring of A₇₀₂ ring is bonded to * in thestructure represented by the formula (72).

In one embodiment, the group represented by the formula (73) is bondedto one or both of A₇₀₁ ring and A₇₀₂ ring.

wherein in the formula (73), Ar₇₀₁ and Ar₇₀₂ are independently asubstituted or unsubstituted aryl group having 6 to 50 ring carbonatoms, or a substituted or unsubstituted monovalent heterocyclic grouphaving 5 to 50 ring atoms; and

L₇₀₁ to L₇₀₃ are independently

-   a single bonded,-   a substituted or unsubstituted arylene group having 6 to 30 ring    carbon atoms,-   a substituted or unsubstituted divalent heterocyclic group having 5    to 30 ring atoms, or-   a divalent linking group formed by bonding 2 to 4 above mentioned    groups.

In one embodiment, in addition to A₇₀₁ ring, the ring carbon atom of thearomatic hydrocarbon ring or the ring atom of the heterocyclic ring ofA₇₀₂ ring is bonded to * in the structure represented by the formula(72). In this case, the structures represented by formula (72) may bethe same or different.

In one embodiment, R₇₀₁ and R₇₀₂ are independently a substituted orunsubstituted aryl group having 6 to 50 ring carbon atoms.

In one embodiment, R₇₀₁ and R₇₀₂ are bonded with each other to form afluorene structure.

In one embodiment, Ar₇₀₁ ring and Ar₇₀₂ ring are substituted orunsubstituted aromatic hydrocarbon rings having 6 to 50 ring carbonatoms, and they are substituted or unsubstituted benzene rings, forexample.

In one embodiment, Ar₇₀₃ ring is a substituted or unsubstituted aromatichydrocarbon ring having 6 to 50 ring carbon atoms, and it is asubstituted or unsubstituted benzene ring, for example.

In one embodiment, X₇₀₁ is O or S.

As specific example of the compound represented by the formula (71), thefollowing compounds can be given, for example. In the following examplecompounds, Me represents methyl group.

(Compound Represented by Formula (81))

The compound represented by the formula (81) is explained below.

wherein, in the formula (81),

A₈₀₁ ring is a ring represented by the formula (82) which is fused to anadjacent ring at an arbitrary position;

A₈₀₂ ring is a ring represented by the formula (83) which is fused to anadjacent ring at an arbitrary position;

two bonds * bond to A₈₀₃ ring at an arbitrary position;

X₈₀₁ and X₈₀₂ are independently C(R₈₀₃)(R₈₀₄), Si(R₈₀₅)(R₈₀₆), an oxygenatom, or a sulfur atom;

A₈₀₃ ring is a substituted or unsubstituted aromatic hydrocarbon ringhaving 6 to 50 ring carbon atoms, or a substituted or unsubstitutedheterocyclic ring having 5 to 50 ring atoms;

Ar₉₀₁ is a substituted or unsubstituted aryl group having 6 to 50 ringcarbon atoms, or a substituted or unsubstituted monovalent heterocyclicgroup having 5 to 50 ring atoms;

R₈₀₁ to R₈₀₆ are independently

-   a hydrogen atom,-   a substituted or unsubstituted alkyl group having 1 to 50 carbon    atoms,-   a substituted or unsubstituted alkenyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted alkynyl group having 2 to 50 carbon    atoms,-   a substituted or unsubstituted cycloalkyl group having 3 to 50 ring    carbon atoms,-   —Si(R₉₀₁)(R₉₀₂)(R₉₀₃),-   —O—(R₉₀₄),-   —S—(R₉₀₅),-   —N(R₉₀₆)(R₉₀₇),-   a halogen atom, a cyano group, a nitro group,-   a substituted or unsubstituted aryl group having 6 to 50 ring carbon    atoms, or-   a substituted or unsubstituted monovalent heterocyclic group having    5 to 50 ring atoms;

R₉₀₁ to R₉₀₇ are as defined in the formula (1);

m801 and m802 are independently an integer of 0 to 2; when these are 2,plural R₈₀₁s or R₆₀₂s may be the same or different;

a801 is an integer of 0 to 2; when a801 is 0 or 1, the structure in theparenthese indicated by “3-a801” may be the same or different from eachother; when a801 is 2, Ar₈₀₁s may be the same or different from eachother.

In one embodiment, Ar₈₀₃ is a substituted or unsubstituted aryl grouphaving 6 to 50 ring carbon atoms.

In one embodiment, A₈₀₃ ring is a substituted or unsubstituted aromatichydrocarbon ring having 6 to 50 ring carbon atoms, and it is asubstituted or unsubstituted benzene ring, a substituted orunsubstituted naphthalene ring, or a substituted or unsubstitutedanthracene ring, for example.

In one embodiment, R₈₀₃ and R₈₀₄ are independently a substituted orunsubstituted alkyl group having 1 to 50 carbon atoms.

In one embodiment, a801 is 1.

As specific example of the compound represented by the formula (81), thefollowing compounds can be given, for example.

Specific examples of the above groups are as described in [Definition]of this specification.

In the organic EL device according to one aspect of the invention, knownmaterials and device configurations may be applied as long as the deviceincludes a cathode, an anode, and an emitting layer disposed between thecathode and the anode, and the emitting layer includes a compoundrepresented by the following formula (1) and one or more compoundsselected from the group consisting of compounds represented by formulas(11), (21), (31), (41), (51), (61), (71) and (81) as described above,and as long as the effect of the invention is not impaired.

In one embodiment, the emitting layer contains a compound represented bythe formula (1A) and a compound represented by the formula (43D).

In one embodiment, the compound represented by the formula (1A) is oneor more selected from the group consisting of the compound representedby the formulas BH-1 to BH-3, BH-5 to BH-13 and BH-15 to BH-17, and thecompound represented by the formula (43D) is one or more selected fromthe group consisting of the compound represented by the formulas BD-9,BD-10, BD-11 and BD-12.

A content of the compound represented by the formula (1) in the emittinglayer is preferably 80 mass % or more and 99 mass % or less based on thetotal mass of the emitting layer.

A content of the one or more compounds selected from the groupconsisting of compounds represented by formulas (11), (21), (31), (41),(51), (61), (71) and (81) is preferably 1 mass % or more and 20 mass %or less based on a total mass of the emitting layer.

One embodiment of the organic EL device preferably has thehole-transporting layer between the anode and the emitting layer.

One embodiment of the organic EL device preferably has theelectron-transporting layer between the cathode and the emitting layer.

Specific examples of a typified device configuration of the organic ELdevice of the invention include structures such as

-   (1) an anode/an emitting layer/a cathode,-   (2) an anode/a hole-injecting layer/an emitting layer/a cathode,-   (3) an anode/an emitting layer/an electron-injecting-transporting    layer/a cathode,-   (4) an anode/a hole-injecting layer/an emitting layer/an    electron-injecting-transporting layer/a cathode,-   (5) an anode/an organic semiconductor layer/an emitting layer/a    cathode,-   (6) an anode/an organic semiconductor layer/an electron barrier    layer/an emitting layer/a cathode,-   (7) an anode/an organic semiconductor layer/an emitting layer/an    adhesion improving layer/a cathode,-   (8) an anode/a hole-injecting-transporting layer/an emitting    layer/an electron-injecting-transporting layer/a cathode,-   (9) an anode/an insulating layer/an emitting layer/an insulating    layer/a cathode,-   (10) an anode/an inorganic semiconductor layer/an insulating    layer/an emitting layer/an insulating layer/a cathode,-   (11) an anode/an organic semiconductor layer/an insulating layer/an    emitting layer/an insulating layer/a cathode,-   (12) an anode/an insulating layer/a hole-injecting-transporting    layer/an emitting layer/an insulating layer/a cathode, and-   (13) an anode/an insulating layer/a hole-injecting-transporting    layer/an emitting layer/an electron-injecting-transporting layer/a    cathode.

Among the above-described structures, a configuration of (8) ispreferably used, but the configuration is not limited thereto,

In this specification, the term “hole-injecting-transporting layer”herein means “at least one of the hole-injecting layer and thehole-transporting layer”, and the term “electron-injecting-transportinglayer” herein means “at least one of the electron-injecting layer andthe electron-transporting layer”.

Hereinbelow, an explanation will be made on elements and materials otherthan the above-mentioned compound constituting each layer that can beused in the organic EL device according to one aspect of the invention.

(Substrate)

The substrate is used as a supporting body of the emitting device. Asthe substrate, glass, quarts, plastic or the like can be used. Further,a flexible substrate may be used. The flexible substrate means asubstrate that can be bent. For example, a plastic substrate made ofpolycarbonate or vinyl polychloride or the like can be given.

(Anode)

In an anode formed on a substrate, it is preferable to use a metalhaving a large work function (specifically, 4.0 eV or more), an alloy,an electric conductive compound, a mixture of these or the like.Specifically, indium oxide-tin oxide (ITO: Indium Tin Oxide), indiumoxide-tin oxide containing silicon or silicon oxide, indium oxide-zincoxide, tungsten oxide, indium oxide containing zinc oxide, graphene, orthe like can be given. In addition, gold (Au), platinum (Pt) or anitride of a metal material (e.g. titanium nitride) or the like can begiven.

(Hole-Injecting Layer)

The hole-injecting layer is a layer containing a substance having a highhole-injecting property. As a substance having a high hole-injectingproperty, a substance selected from molybdenum oxide, titanium oxide,vanadium oxide, rhenium oxide, ruthenium oxide, chromium oxide,zirconium oxide, hafnium oxide, tantalum oxide, silver oxide, tungstenoxide, manganese oxide, an aromatic amine compound, a polymer compound(oligomer, dendrimer, polymer, etc.) or the like can also be used

(Hole-Transporting Layer)

The hole-transporting layer is a layer containing a substance having ahigh hole-transporting property. For the hole-transporting layer,aromatic amine compounds, carbazole derivatives, anthracene derivativesand the like can be used. Polymer compounds such as poly(N-vinylcarbazole) (abbreviation: PVK) and poly(4-vinyltriphenylamine)(abbreviation: PVTPA) can also be used. However, any substance otherthan these may be used as long as it is a substance having a highertransporting property for holes than electrons. Note that the layercontaining a substance having a high hole-transporting property is notlimited to a single layer, but may be a stacked body of two or morelayers made of the above substances.

(Guest Material of the Emitting Layer)

The emitting layer is a layer that comprises a substance having highluminous property, and various materials can be used. For example, asthe substance having high luminous property, a fluorescent compound thatemits fluorescent light or a phosphorescent compound that emitsphosphorescent light can be used. The fluorescent compound is a compoundcapable of emitting light from a singlet excited state and thephosphorescent compound is a compound capable of emitting light from atriplet excited state.

As a blue fluorescent material that can be used for the emitting layer,pyrene derivatives, styrylamine derivatives, chrysene derivatives,fluoranthene derivatives, fluorene derivatives, diamine derivatives,triaryiamine derivatives and the like can be used. An aromatic aminederivative or the like can be used as a green fluorescent light-emittingmaterial that can be used in the emitting layer. As a red fluorescentmaterial which can be used in emitting layer, a tetracene derivative, adiamine derivative or the like can be used.

Metal complexes such as iridium complexes, osmium complexes, platinumcomplexes and the like are used as the blue phosphorescent material thatcan be used in the emitting layer. An iridium complex or the like isused as a green phosphorescent material that can be used in the emittinglayer. Metal complexes such as iridium complexes, platinum complexes,terbium complexes, europium complexes and the like are used as redphosphorescent materials that can be used in the emitting layer.

(Host Material of Emitting Layer)

The emitting layer may have a structure in which the substance havinghigh luminescent property (guest material) described above is dispersedin another substance (host material). Various materials other than thecompound represented by the formula (1) (for example, the compoundrepresented by the formula (1A)) can be used as substances fordispersing substances with high luminescent properties, and it ispreferable to use a material having a high lowest unoccupied molecularorbital level (LUMO level) and a low highest occupied molecular orbitallevel (HOMO level), rather than a material having a high luminousproperty.

As a substance (host material) for dispersing a substance having a highluminous property, 1) a metal complex such as an aluminum complex, aberyllium complex or a zinc complex, 2) a heterocyclic compound such asan oxadiazole derivative, a benzimidazole derivative, a phenanthrolinederivative or the like, 3) a fused aromatic compound such as a carbazolederivative, an anthracene derivative, a phenanthrene derivative, apyrene derivative or a chrysene derivative, and 4) an aromatic aminecompound such as a triarylamine derivative or a fused polycyclicaromatic amine derivative are used.

(Electron-Transporting Layer)

The electron-transporting layer is a layer containing a substance havinga high electron-transporting property. For the electron-transportinglayer, 1) a metal complex such as an aluminum complex, a berylliumcomplex, or a zinc complex, 2) a heteroaromatic compound such as animidazole derivative, a benzimidazole derivative, an azine derivative, acarbazole derivative or a phenanthroline derivative, and 3) a polymercompound can be used.

(Electron-Injecting Layer)

The electron-injection layer is a layer containing a substance having ahigh electron-injection property. For the electron-injection layer,alkali metals, alkaline earth metals or a compound thereof such aslithium (Li), ytterbium (Yb), lithium fluoride (LiF), cesium fluoride(CsF), calcium fluoride (CaF₂), metal complex compound such as8-quinolinolato lithium (Liq), lithium oxide (LiOx) or the like can beused.

(Cathode)

It is preferable to use a metal, an alloy, an electrically conductivecompound, a mixture thereof, or the like having a small work function(specifically, 3.8 eV or less) for the cathode. Specific examples ofsuch cathode material include elements belonging to Group 1 or Group 2of the periodic table of elements, that is, alkali metals such aslithium (Li) and cesium (Cs), alkaline earth metals such as magnesium(Mg), calcium (Ca), and strontium (Sr),

an alloy containing these metals (for example, MgAg and AlLi), a rareearth metal such as europium (Eu) and ytterbium (Yb), and an alloycontaining a rare earth metal.

In the organic EL device according to one aspect of the invention, themethod for forming each layer is not particularly restricted. Aconventionally known forming method such as a vacuum deposition method,a spin coating method or the like can be used. Each layer such as theemitting layer or the like can be formed by a vacuum deposition method,a molecular beam evaporation method (MBE method), or a known coatingmethod such as a dipping method, a solution spin coating method, acasting method, a bar coating method, or the like, that uses a solutionof a material forming each layer dissolved in a solvent.

In the organic EL device according to one aspect of the invention, thethickness of each layer is not particularly restricted. In general, inorder to suppress occurrence of defects such as pinholes and to suppressthe applied voltage and to improve luminous efficiency, the thickness isnormally preferably in a range of several nm to 1 μm.

[Electronic Device]

The electronic device according to one aspect of the invention ischaracterized in that it is provided with the organic EL deviceaccording to one aspect of the invention. Specific examples of theelectronic device includes a display element such as an organic EL panelmodule; a display such as a TV, a mobile phone or a PC; and emittingdevices such as lightings and lights for automobiles or the like.

EXAMPLES

Now, the invention will be explained in detail with reference toExamples and Comparative Examples. However, it should be understood thatthe invention be not restricted at all by these Examples.

Synthesis Example 1 [Synthesis of Compound BH-1] (Synthesis ofIntermediate 1)

Under argon atmosphere, 75 mL of toluene, 75 mL of dimethoxyethane, and75 mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 6.4 g (52.5 mmol) of phenylboronicacid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, and the mixture was refluxedand stirred with heat for 10 hours,

After completion of the reaction, the reaction solution was cooled toroom temperature. The sample of the reaction mixture was transferred toa separation funnel and extracted with dichloromethane. The organicphase was dried over MgSO₄, followed by filtration and concentration.The concentrated residue was purified by silica gel columnchromatography to obtain 10.9 g of white solid. The obtained compoundwas subjected to FD-MS analysis, and it was identified as Intermediate 1below (yield: 83%).

(Synthesis of Intermediate 2)

A solution of 5.3 g (20.0 mmol) of Intermediate 1 dissolved in 120 mL ofdichloromethane was dropwise added at room temperature to a solution of3.2 g (20.0 mmol) of bromine dissolved in 12 mL of dichloromethane,followed by stirring for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and thenwith water, and the separated organic phase was dried over MgSO₄,followed by filtration and concentration.

The concentrated residue was suspended in 100 mL of methanol, and theprecipitated crystals were collected to obtain 6.5 g of white solid. Theobtained compound was subjected to ED-MS analysis, and was identified asIntermediate 2 below (yield: 95%).

(Synthesis of Compound BH-1)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 1.7g (5.0 mmol) of Intermediate 2, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-2-boronic acid, and 0.1g (0.1 mmol) ofPd[PPh₃]₄, and refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funneland extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.7 gof white sold. The obtained compound was subjected to FD-MS analysis,and was identified as Compound BH-1 below (yield: 70%).

Synthesis Example 2 [Synthesis of Compound BH-2] (Synthesis ofIntermediate 3)

Under argon atmosphere, 75 of toluene, 75 mL of dimethoxyethane, and 75mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 9.0 g (52.5 mmol) of 1-naphthaleneboronic acid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, and the reactionmixture was refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funneland extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 13.3g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 3 below (yield: 85%).

(Synthesis of Intermediate 4)

A solution of 6.3 g (20.0 mmol) of Intermediate 3 dissolved in 120 mL ofdichloromethane was dropwise added at room temperature to a solution of3.2 g (20.0 mmol) of bromine dissolved in 12 mL of dichloromethane, andstirred for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and then,washed with water three times. The organic phase was dried over MgSO₄,followed by filtration and concentration,

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 7.5 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 4 below (yield: 96%).

(Synthesis of Compound BH-2)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 2.0g (5.0 mmol) of Intermediate 4, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-2-boronic acid, and 0.1 g (0.1 mmol) ofPd[PPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funneland extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.9 gof white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-2 below (yield: 73%).

Synthesis Example 3 (Synthesis of Compound BH-3)

The same reaction was conducted in the same manner as in SynthesisExample 1 except that 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-1-boronic add was used in place ofbenzo[b]naphtho[2,3-d]furan-2-boronic add, to obtain 1.4 g of whitecrystals. The obtained compound was subjected to FD-MS analysis, andidentified as Compound BH-3 below (yield: 57%).

Synthesis Example 4 (Synthesis of Compound BH-4)

The same reaction was conducted in the same manner as in SynthesisExample 1 except that 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-3-boronic acid was used in place ofbenzo[b]naphtho[2,3-d]furan-2-boronic acid, to obtain 1.8 g of whitecrystals. The obtained compound was subjected to FD-MS analysis, andidentified as Compound BH-4 below (yield: 74%).

Synthesis Example 5 [Synthesis of Compound BH-5] (Synthesis ofIntermediate 5)

Under argon atmosphere, 75 mL of toluene, 75 mL of dimethoxyethane, and75 mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 13.0 g (52.5 mmol) of4-(1-naphthyl)phenylboronic acid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄,and the reaction mixture was refluxed and stirred with heat for 10hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funneland extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 15.6g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 5 below (yield: 80%).

(Synthesis of Intermediate 6)

A solution of 7.8 g (20.0 mmol) of Intermediate 5 dissolved in 120 mL ofdichloromethane was dropwise added at room temperature to a solution of3.2 g (20.0 mmol) of bromine dissolved in 12 ml of dichloromethane, andthe reaction mixture was stirred for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and withwater three times. The organic phase was dried over MgSO₄, followed byfiltration and concentration.

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 8.6 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 6 below (yield: 92%).

(Synthesis of Compound BH-5)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 2.3g (5.0 mmol) of Intermediate 6, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-2-boronic acid, and 0.1 g (0.1 mmol) ofPd[PPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 2.1 gof white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-5 below (yield: 68%).

Synthesis Example 6 (Synthesis of Compound BH-6)

The reaction was conducted in the same manner as in Synthesis Example 1except that 1.4 g (5.3 mmol) of benzo[b]naphtho[1,2-d]furan-10-boronicacid was used in place of benzo[b]naphtho[2,3-d]furan-2-boronic acid, toobtain 1.7 g of white crystals. The obtained compound was subjected toFD-MS analysis, and identified as Compound BH-6 below (yield: 71%).

Synthesis Example 7 (Synthesis of Compound BH-7)

The reaction was conducted in the same manner as in Synthesis Example 1except that 1.4 g (5.3 mmol) of benzo[b]naphtho[2,1-d]furan-8-boronicacid was used in place of benzo[b]naphtho[2,3-d]furan-2-boronic acid, toobtain 1.6 g of white crystals. The obtained compound was subjected toFD-MS analysis, and identified as Compound BH-7 below (yield: 65%).

Synthesis Example 8 [Synthesis of Compound BH-8] (Synthesis ofIntermediate 7)

Under argon atmosphere, 75 ml of toluene, 75 mL of dimethoxyethane, and75 mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of3-biphenylboronic acid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, and thereaction mixture was refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 13.6g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 7 below (yield: 80%).

(Synthesis of Intermediate 8)

A solution of 6.8 g (20.0 mmol) of Intermediate 7 dissolved in 120 mL ofdichloromethane was dropwise added to a solution of 3.2 g (20.0 mmol) ofbromine dissolved in 12 mL of dichloromethane, and the reaction mixturewas stirred for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and then,with water three times. The organic phase was dried over MgSO₄, followedby filtration and concentration.

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 8.0 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 8 below (yield: 96%).

(Synthesis of Compound BH-8)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 2.1g (5.0 mmol) of Intermediate 8, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-1-boronic acid, and 0.1 g (0.1 mmol) ofPd[PPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.7 gof white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-8 below (yield: 60%).

Synthesis Example 9 (Synthesis of Compound BH-9)

The reaction was conducted in the same manner as in Synthesis Example 1except that 1.4 g (5.3 mmol) of benzo[b]naphtho[2,1-d]furan-7-boronicacid was used in place of benzo[b]naphtho[2,3-d]furan-2-boronic acid, toobtain 1.6 g of white crystals. The obtained compound was subjected toFD-MS analysis, and identified as Compound BH-9 below (yield: 65%).

Synthesis Example 10 [Synthesis of Compound BH-10] (Synthesis ofIntermediate 9)

Under argon atmosphere, 75 ml of toluene, 75 mL of dimethoxyethane, and75 mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of4-biphenylboronic acid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, and thereaction mixture was refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 14.1g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 9 below (yield: 83%).

(Synthesis of Intermediate 10)

A solution of 6.8 g (20.0 mmol) of Intermediate 9 dissolved in 120 mL ofdichloromethane was dropwise added to a solution of 3.2 g (20.0 mmol) ofbromine dissolved in 12 mL of dichloromethane, and the reaction mixturewas stirred for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and then,with water three times. The organic phase was dried over MgSO₄, followedby filtration and concentration.

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 8.0 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 10 below (yield: 96%).

(Synthesis of Compound BH-10)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 2.1g (5.0 mmol) of Intermediate 10, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-1-boronic add, and 0.1 g (0.1 mmol) ofPd[PPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.4 gof white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-10 below (yield: 51%).

Synthesis Example 11 (Synthesis of Compound BH-11)

The reaction was conducted in the same manner as in Synthesis Example 8except that 1.4 q (5.3 mmol) of benzo[b]naphtho[2,1]furan-7-boronic acidwas used in place of benzo[b]naphtho[2,3-d]furan-1-boronic acid, toobtain 1.4 g of white crystals. The obtained compound was subjected toFD-MS analysis, and identified as Compound BH-11

Synthesis Example 12 (Synthesis of Compound BH-12)

The reaction was conducted in the same manner as in Synthesis Example 1except that 1.8 g (5.3 mmol) of3-(benzo[b]naphtho[2,3-d]furan-1-yl)phenylboronic acid was used in placeof benzo[b]naphtho[2,3-d]furan-2-boronic acid, to obtain 1.5 g of whitecrystals. The obtained compound was subjected to FD-MS analysis, andidentified as Compound BH-12 below (yield: 53%).

Synthesis Example 13 [Synthesis of Compound BH-13] (Synthesis ofIntermediate 11)

Under argon atmosphere, 75 ml of toluene, 75 mL of dimethoxyethane, and75 mL (150.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 13.3 g(50.0 mmol) of 9-bromoanthracene-d9, 10.4 g (52.5 mmol) of2-biphenylboronic acid, and 1.2 g (1.00 mmol) of Pd[PPh₃]₄, and thereaction mixture was refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 10.9g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 11 below (yield: 64%).

(Synthesis of Intermediate 12)

A solution of 6.8 g (20.0 mmol) of Intermediate 11 dissolved in 120 mLof dichloromethane was dropwise added to a solution of 3.2 g (20.0 mmol)of bromine dissolved in 12 mL of dichloromethane, and the reactionmixture was stirred for one hour. After completion of the reaction, thesample was transferred to a separation funnel, and washed with a 2MNa₂S₂O₃ aqueous solution. Subsequently, the organic phase was washedwith 10% Na₂CO₃, and then, with water three times. The organic phase wasdried over MgSO₄, followed by filtration and concentration.

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 8.0 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 12 below (yield: 96%).

(Synthesis of Compound BH-13)

Under argon atmosphere, 7.5 mL of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 2.1g (5.0 mmol) of Intermediate 12, 1.4 g (5.3 mmol) ofbenzo[b]naphtho[2,3-d]furan-2-boronic acid, and 0.1 g (0.1 mmol) ofPd[PPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.7 gof white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-13 below (yield: 60%).

Synthesis Example 15 (Synthesis of Compound BH-15)

The reaction was conducted in the same manner as in Synthesis Example 1except that 1.8 g (5.3 mmol) of4-(benzo[b]naphtho[2,3-d]furan-1-yl)phenylboronic acid was used in placeof benzo[b]naphtho[2,3-d]furan-2-boronic acid, to obtain 1.5 g of whitecrystals. The obtained compound was subjected to FD-MS analysis, andidentified as Compound BH-15 below (yield: 55%).

Synthesis Example 16 [Synthesis of Compound BH-16] (Synthesis ofIntermediate 13)

Under argon atmosphere, 7.5 ml of toluene, 7.5 mL of dimethoxyethane,and 7.5 mL (15.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to1.33 g (5.00 mmol) of 9-bromoanthracene-d9, 0.67 g (5.25 mmol) ofphenyl-d5-boronic acid, and 0.12 g (0.10 mmol) of Pd[PPh₃]₄, and thereaction mixture was refluxed and stirred with heat for 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 1.07g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Intermediate 13 below (yield: 80%).

(Synthesis of Intermediate 14)

A solution of 1.07 g (4.0 mmol) of Intermediate 13 dissolved in 25 mL ofdichloromethane was dropwise added to a solution of 0.64 g (4.0 mmol) ofbromine dissolved in 3 mL of dichloromethane, and the reaction mixturewas stirred for one hour.

After completion of the reaction, the sample was transferred to aseparation funnel, and washed with a 2M Na₂S₂O₃ aqueous solution.Subsequently, the organic phase was washed with 10% Na₂CO₃, and then,with water three times. The organic phase was dried over MgSO₄, followedby filtration and concentration,

The concentrated residue was suspended in 100 mL of methanol, andprecipitated crystals were collected to obtain 1.3 g of white solid. Theobtained compound was subjected to FD-MS analysis, and identified asIntermediate 14 below (yield: 95%).

(Synthesis of Compound BH-16)

Under argon atmosphere, 5 mL of toluene, 5 mL of dimethoxyethane, and 5mL (10.0 mmol) of a 2M Na₂CO₃ aqueous solution were added to 0.87 g (2.5mmol) of Intermediate 14, 0.69 g (2.65 mmol) ofbenzo[b]naphtho[2,3-d]furan-Z-boronic add, and 0.06 g (0.05 mmol) ofPd[RPh₃]₄, and the reaction mixture was refluxed and stirred with heatfor 10 hours.

After completion of the reaction, the reaction solution was cooled toroom temperature, and the sample was transferred to a separation funnel,and extracted with dichloromethane. The organic phase was dried overMgSO₄, followed by filtration and concentration. The concentratedresidue was purified by silica gel column chromatography to obtain 0.87g of white solid. The obtained compound was subjected to FD-MS analysis,and identified as Compound BH-16 below (yield: 72%).

Synthesis Example 17 (Synthesis of Compound BH-17)

The reaction was conducted in the same manner as in Synthesis Example 2except that 1.4 g (5.3 mmol) of benzo[b]naphtho[1,2-d]furan-10-boronicacid was used in place of benzo[b]naphtho[2.3-d]furan-2-boronic acid, toobtain 1.5 g of white crystals. The obtained compound was subjected toFD-MS analysis, and identified as Compound BH-17 below (yield: 56%).

Example 1 (Fabrication of Organic EL Device)

A glass substrate of 25 mm by 75 mm by 1.1 mm thick with an ITOtransparent electrode (anode) (manufactured by GEOMATEC Co., Ltd.) wassubjected to ultrasonic cleaning with isopropyl alcohol for 5 minutes,and then subjected to UV-ozone cleaning for 30 minutes. The thickness ofthe ITO was 130 nm.

The cleaned glass substrate with a transparent electrode was mounted ina substrate holder of a vacuum vapor deposition apparatus. First, thecompound HI was deposited on the surface where the transparent electrodewas formed so as to cover the transparent electrode, thereby to form a 5nm-thick HI film was formed. This HI film serves as a hole-injectinglayer.

Subsequent to the formation of the HI film, the compound HT-1 wasdeposited, whereby a 80 nm-thick HT-1 film was formed on the HI film,This HT-1 film serves as a hole-transporting layer (firsthole-transporting layer).

Subsequent to the formation of the HT-1 film, the compound HT-2 wasdeposited, whereby a 10 nm-thick HT-2 film was formed on the HT-1 film.This HT-2 film serves as an electron blocking layer (secondhole-transporting layer).

On the HT-2 film, compound BH-1 (host material) and compound BD-1(dopant material) were co-deposited such that the amount ratio of BD-1(mass ratio) became 4 mass %, whereby a 25 nm-thick BH-1:BD-1 film wasformed. The BH-1:BD-1 film serves as an emitting layer.

On the emitting layer, compound ET-1 was deposited, whereby a 10nm-thick ET-1 film was formed. This ET-1 film serves as a hole barrierlayer.

On the ET-1 film, compound ET-2 was deposited, whereby a 15 nm-thickET-2 film was formed. This ET-2 film serves as an electron transportinglayer. On this ET-2 film, LiF was deposited, whereby a 1 nm-thick LiFfilm. On this LiF film, metal Al was deposited, whereby a 80 nm-thickmetal cathode was formed. By the above-mentioned procedures, an organicEL device was fabricated.

The resultant organic EL device has the following layer structure:ITO(130)/HI(5)/HT-1(80)/HT-2(10)/BH-1:BD-1(25: 4 mass%)/ET-1(10)/ET-2(15)/LiF(1)/Al(80).

The numerical value in the parenthesis indicates the film thickness(unit: nm).

Materials used in Example 1 and the below-mentioned Examples andComparative Examples are shown below.

(Evaluation of Organic EL Device)

A voltage was applied to the resulting organic EL device such that thecurrent density became 50 mA/cm², and the time taken until the luminancebecame 95% of the initial luminance (lifetime, LT95) were measured. Theresults are shown in Table 1.

Further, the CIE1931 chromaticity coordinates (CIEx and CIEy) of theresulting organic EL device at the time when a voltage was appliedthereto such that the current density became 10 mA/cm², were determinedfrom a spectral radiance spectrum measured by means of a spectralradiance meter CS-1000 (manufactured by Konica Minolta, Inc.). Theresults are shown in Table 1.

Comparative Example 1

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asthe host material, and evaluated. The results are shown in Table 1.

TABLE 1 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 1 BH-1 BD-1 98 0.139 0.091 Comparative Example1 BH-1-a BD-1 60 0.139 0.091

Example 2 and Comparative Example 2

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 2 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 2.

TABLE 2 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 2 BH-1 BD-2 33 0.137 0.068 Comparative Example2 BH-1-a BD-2 20 0.137 0.068

Example 3 and Comparative Example 3

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 3 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 3.

TABLE 3 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 3 BH-2 BD-1 65 0.139 0.090 Comparative Example3 BH-2-a BD-1 40 0.139 0.090

Example 4 and Comparative Example 4

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 4 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 4.

TABLE 4 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 4 BH-2 BD-2 23 0.137 0.067 Comparative Example4 BH-2-a BD-2 13 0.137 0.067

Example 5 and Comparative Example 5

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 5 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 5.

TABLE 5 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 5 BH-3 BD-1 110 0.139 0.091 ComparativeExample 5 BH-3-a BD-1 69 0.139 0.091

Example 6 and Comparative Example 6

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 6 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 6.

TABLE 6 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 6 BH-3 BD-2 40 0.137 0.068 Comparative Example6 BH-3-a BD-2 25 0.137 0.068

Example 7 and Comparative Example 7

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 7 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 7.

TABLE 7 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 7 BH-4 BD-1 60 0.139 0.090 Comparative Example7 BH-4-a BD-1 35 0.139 0.090

Example 8 and Comparative Example 8

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in Table 8 was used as materials forthe emitting layer, and evaluated. The results are shown in Table 8.

TABLE 8 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 8 BH-4 BD-2 23 0.137 0.067 Comparative Example8 BH-4-a BD-2 13 0.137 0.067

Example 11 and Comparative Example 11

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 9.

TABLE 9 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 11 BH-1 BD-3 117 0.140 0.080 ComparativeExample 11 BH-1-a BD-3 73 0.140 0.080

Example 12 and Comparative Example 12

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 10.

TABLE 10 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 12 BH-2 BD-3 74 0.140 0.080 ComparativeExample 12 BH-2-a BD-3 46 0.140 0.080

Example 13 and Comparative Example 13

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 11.

TABLE 11 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 13 BH-3 BD-3 130 0.140 0.080 ComparativeExample 13 BH-3-a BD-3 82 0.140 0.081

Example 14 and Comparative Example 14

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 12.

TABLE 12 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 14 BH-4 BD-3 74 0.140 0.080 ComparativeExample 14 BH-4-a BD-3 42 0.140 0.080

Example 15 and Comparative Example 15

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 13.

TABLE 13 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 15 BH-5 BD-3 68 0.140 0.080 ComparativeExample 15 BH-5-a BD-3 49 0.140 0.080

Example 16 and Comparative Example 16

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 14.

TABLE 14 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 16 BH-6 BD-3 141 0.140 0.080 ComparativeExample 16 BH-6-a BD-3 90 0.140 0.080

Example 17 and Comparative Example 17

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 15.

TABLE 15 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 17 BH-7 BD-3 127 0.140 0.080 ComparativeExample 17 BH-7-a BD-3 68 0.140 0.080

Example 18 and Comparative Example 18

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 16.

TABLE 16 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 18 BH-8 BD-3 126 0.140 0.080 ComparativeExample 18 BH-8-a BD-3 73 0.140 0.080

Example 19 and Comparative Example 19

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 17.

TABLE 17 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 19 BH-9 BD-3 128 0.140 0.080 ComparativeExample 19 BH-9-a BD-3 76 0.140 0.080

Example 21 and Comparative Example 21

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 18.

TABLE 18 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 21 BH-1 BD-4 137 0.135 0.098 ComparativeExample 21 BH-1-a BD-4 86 0.135 0.098

Example 22 and Comparative Example 22

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 19.

TABLE 19 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 22 BH-2 BD-4 94 0.135 0.098 ComparativeExample 22 BH-2-a BD-4 58 0.135 0.098

Example 23 and Comparative Example 23

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 20.

TABLE 20 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 23 BH-3 BD-4 152 0.135 0.098 ComparativeExample 23 BH-3-a BD-4 100 0.135 0.098

Example 24 and Comparative Example 24

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 21.

TABLE 21 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 24 BH-4 BD-4 82 0.135 0.098 ComparativeExample 24 BH-4-a BD-4 53 0.135 0.098

Example 25 and Comparative Example 25

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 22.

TABLE 22 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 25 BH-5 BD-4 77 0.135 0.098 ComparativeExample 25 BH-5-a BD-4 57 0.135 0.098

Example 26 and Comparative Example 26

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 23.

TABLE 23 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 26 BH-6 BD-4 172 0.135 0.098 ComparativeExample 26 BH-6-a BD-4 100 0.135 0.098

Example 27 and Comparative Example 27

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 24.

TABLE 24 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 27 BH-7 BD-4 142 0.135 0.099 ComparativeExample 27 BH-7-a BD-4 84 0.135 0.098

Example 28 and Comparative Example 28

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 25.

TABLE 25 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 28 BH-8 BD-4 147 0.135 0.098 ComparativeExample 28 BH-8-a BD-4 85 0.135 0.098

Example 29 and Comparative Example 29

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 26.

TABLE 26 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 29 BH-9 BD-4 150 0.135 0.098 ComparativeExample 29 BH-9-a BD-4 90 0.135 0.098

Example 31 and Comparative Example 31

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 27.

TABLE 27 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 31 BH-1 BD-5 142 0.135 0.086 ComparativeExample 31 BH-1-a BD-5 86 0.135 0.086

Example 32 and Comparative Example 32

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 28.

TABLE 28 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 32 BH-2 BD-5 92 0.135 0.086 ComparativeExample 32 BH-2-a BD-5 59 0.135 0.086

Example 33 and Comparative Example 33

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 29.

TABLE 29 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 33 BH-3 BD-5 163 0.135 0.086 ComparativeExample 33 BH-3-a BD-5 99 0.135 0.086

Example 34 and Comparative Example 34

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 30.

TABLE 30 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 34 BH-4 BD-5 83 0.135 0.086 ComparativeExample 34 BH-4-a BD-5 51 0.135 0.086

Example 35 and Comparative Example 35

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 31.

TABLE 31 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 35 BH-5 BD-5 81 0.135 0.086 ComparativeExample 35 BH-5-a BD-5 56 0.135 0.086

Example 36 and Comparative Example 36

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 32.

TABLE 32 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 36 BH-6 BD-5 173 0.135 0.086 ComparativeExample 36 BH-6-a BD-5 97 0.135 0.086

Example 37 and Comparative Example 37

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 33.

TABLE 33 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 37 BH-7 BD-5 142 0.135 0.085 ComparativeExample 37 BH-7-a BD-5 84 0.135 0.086

Example 38 and Comparative Example 38

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 34.

TABLE 34 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 38 BH-8 BD-5 149 0.135 0.086 ComparativeExample 38 BH-8-a BD-5 94 0.135 0.086

Example 39 and Comparative Example 39

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 35.

TABLE 35 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 39 BH-9 BD-5 152 0.135 0.086 ComparativeExample 39 BH-9-a BD-5 90 0.135 0.086

Example 41 and Comparative Example 41

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 36.

TABLE 36 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 41 BH-1 BD-6 170 0.135 0.080 ComparativeExample 41 BH-1-a BD-6 101 0.135 0.080

Example 42 and Comparative Example 42

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 37.

TABLE 37 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 42 BH-2 BD-6 121 0.135 0.080 ComparativeExample 42 BH-2-a BD-6 70 0.135 0.080

Example 43 and Comparative Example 43

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 38.

TABLE 38 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 43 BH-3 BD-6 205 0.135 0.080 ComparativeExample 43 BH-3-a BD-6 123 0.135 0.080

Example 44 and Comparative Example 44

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 39.

TABLE 39 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 44 BH-4 BD-6 108 0.135 0.080 ComparativeExample 44 BH-4-a BD-6 62 0.135 0.080

Example 45 and Comparative Example 45

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 40.

TABLE 40 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 45 BH-5 BD-6 99 0.135 0.080 ComparativeExample 45 BH-5-a BD-6 71 0.135 0.080

Example 46 and Comparative Example 46

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 41.

TABLE 41 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 46 BH-6 BD-6 214 0.135 0.081 ComparativeExample 46 BH-6-a BD-6 125 0.135 0.080

Example 47 and Comparative Example 47

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 42.

TABLE 42 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 47 BH-7 BD-6 175 0.135 0.080 ComparativeExample 47 BH-7-a BD-6 106 0.135 0.080

Example 48 and Comparative Example 48

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 43.

TABLE 43 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 48 BH-8 BD-6 183 0.135 0.081 ComparativeExample 48 BH-8-a BD-6 111 0.135 0.080

Example 49 and Comparative Example 49

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 44.

TABLE 44 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 49 BH-9 BD-6 192 0.135 0.080 ComparativeExample 49 BH-9-a BD-6 115 0.135 0.080

Example 51 and Comparative Example 51

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 45.

TABLE 45 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 51 BH-1 BD-7 210 0.136 0.090 ComparativeExample 51 BH-1-a BD-7 127 0.136 0.090

Example 52 and Comparative Example 52

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 46.

TABLE 46 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 52 BH-2 BD-7 143 0.136 0.090 ComparativeExample 52 BH-2-a BD-7 80 0.136 0.090

Example 53 and Comparative Example 53

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 47.

TABLE 47 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 53 BH-3 BD-7 236 0.136 0.090 ComparativeExample 53 BH-3-a BD-7 150 0.136 0.090

Example 54 and Comparative Example 54

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 48.

TABLE 48 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 54 BH-4 BD-7 119 0.136 0.090 ComparativeExample 54 BH-4-a BD-7 74 0.136 0.090

Example 55 and Comparative Example 55

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 49.

TABLE 49 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 55 BH-5 BD-7 121 0.136 0.090 ComparativeExample 55 BH-5-a BD-7 85 0.136 0.090

Example 56 and Comparative Example 56

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 50.

TABLE 50 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 56 BH-6 BD-7 251 0.136 0.090 ComparativeExample 56 BH-6-a BD-7 137 0.136 0.090

Example 57 and Comparative Example 57

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 51.

TABLE 51 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 57 BH-7 BD-7 210 0.136 0.090 ComparativeExample 57 BH-7-a BD-7 130 0.136 0.091

Example 58 and Comparative Example 58

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 52.

TABLE 52 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 58 BH-8 BD-7 221 0.136 0.090 ComparativeExample 58 BH-8-a BD-7 135 0.136 0.090

Example 59 and Comparative Example 59

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 53.

TABLE 53 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 59 BH-9 BD-7 225 0.136 0.090 ComparativeExample 59 BH-9-a BD-7 140 0.136 0.090

Example 61 and Comparative Example 61

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 54.

TABLE 54 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 61 BH-1 BD-8 107 0.144 0.060 ComparativeExample 61 BH-1-a BD-8 66 0.144 0.061

Example 62 and Comparative Example 62

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 55.

TABLE 55 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 62 BH-2 BD-8 68 0.144 0.061 ComparativeExample 62 BH-2-a BD-8 46 0.144 0.061

Example 63 and Comparative Example 63

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 56.

TABLE 56 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 63 BH-3 BD-8 120 0.144 0.061 ComparativeExample 63 BH-3-a BD-8 76 0.144 0.061

Example 64 and Comparative Example 64

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 57.

TABLE 57 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 64 BH-4 BD-8 69 0.144 0.061 ComparativeExample 64 BH-4-a BD-8 40 0.144 0.061

Example 65 and Comparative Example 65

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 58.

TABLE 58 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 65 BH-5 BD-8 64 0.144 0.061 ComparativeExample 65 BH-5-a BD-8 49 0.144 0.061

Example 66 and Comparative Example 66

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 59.

TABLE 59 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 66 BH-6 BD-8 137 0.144 0.061 ComparativeExample 66 BH-6-a BD-8 83 0.144 0.061

Example 67 and Comparative Example 67

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 60.

TABLE 60 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 67 BH-7 BD-8 118 0.144 0.061 ComparativeExample 67 BH-7-a BD-8 66 0.144 0.061

Example 68 and Comparative Example 68

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 61.

TABLE 61 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 68 BH-8 BD-8 119 0.144 0.061 ComparativeExample 68 BH-8-a BD-8 70 0.144 0.061

Example 69 and Comparative Example 69

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 62.

TABLE 62 Emitting layer Host Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 69 BH-9 BD-8 120 0.144 0.061 ComparativeExample 69 BH-9-a BD-8 75 0.144 0.061

Example 70 and Comparative Example 70

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 63.

TABLE 63 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 70 BH-1 BD-9 96 0.141 0.056 ComparativeExample 70 BH-1-a BD-9 72 0.141 0.056

Example 71 and Comparative Example 71

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 64.

TABLE 64 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 71 BH-2 BD-9 78 0.141 0.056 ComparativeExample 71 BH-2-a BD-9 50 0.141 0.056

Example 72 and Comparative Example 72

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 65.

TABLE 65 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 72 BH-3 BD-9 112 0.141 0.056 ComparativeExample 72 BH-3-a BD-9 81 0.141 0.056

Example 73 and Comparative Example 73

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 66.

TABLE 66 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 73 BH-5 BD-9 67 0.141 0.056 ComparativeExample 73 BH-5-a BD-9 51 0.141 0.056

Example 74 and Comparative Example 74

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 67.

TABLE 67 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 74 BH-6 BD-9 130 0.141 0.056 ComparativeExample 74 BH-6-a BD-9 85 0.141 0.056

Example 75 and Comparative Example 75

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 68.

TABLE 68 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 75 BH-7 BD-9 109 0.141 0.056 ComparativeExample 75 BH-7-a BD-9 73 0.141 0.056

Example 76 and Comparative Example 76

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 69.

TABLE 69 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 76 BH-8 BD-9 113 0.141 0.057 ComparativeExample 76 BH-8-a BD-9 74 0.141 0.057

Example 77 and Comparative Example 77

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 70.

TABLE 70 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 77 BH-9 BD-9 112 0.141 0.057 ComparativeExample 77 BH-9-a BD-9 79 0.141 0.057

Example 78 and Comparative Example 78

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 71.

TABLE 71 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 78 BH-10 BD-9 107 0.141 0.057 ComparativeExample 78 BH-10-a BD-9 70 0.141 0.057

Example 79 and Comparative Example 79

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 72.

TABLE 72 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 79 BH-11 BD-9 108 0.141 0.057 ComparativeExample 79 BH-11-a BD-9 78 0.141 0.057

Example 80 and Comparative Example 80

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 73.

TABLE 73 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 80 BH-12 BD-9 111 0.141 0.056 ComparativeExample 80 BH-12-a BD-9 78 0.141 0.056

Example 81 and Comparative Example 81

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 74.

TABLE 74 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 81 BH-13 BD-9 60 0.141 0.056 ComparativeExample 81 BH-13-a BD-9 40 0.141 0.056

Example 82 and Comparative Example 82

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 75.

TABLE 75 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 82 BH-15 BD-9 67 0.141 0.056 ComparativeExample 82 BH-15-a BD-9 43 0.141 0.056

Example 83

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 76.

TABLE 76 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 83 BH-16 BD-9 99 0.141 0.056

Example 84 and Comparative Example 84

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 77.

TABLE 77 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Exampie 84 BH-17 BD-9 129 0.141 0.056 ComparativeExample 84 BH-17-a BD-9 88 0.141 0.056

Example 85 and Comparative Example 85

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 78.

TABLE 78 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 85 BH-1 BD-10 172 0.133 0.078 ComparativeExample 85 BH-1-a BD-10 122 0.133 0.078

Example 86 and Comparative Example 86

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 79.

TABLE 79 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 86 BH-2 BD-10 118 0.133 0.078 ComparativeExample 86 BH-2-a BD-10 82 0.133 0.078

Example 87 and Comparative Example 87

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 80.

TABLE 80 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 87 BH-3 BD-10 199 0.133 0.078 ComparativeExample 87 BH-3-a BD-10 138 0.133 0.078

Example 88 and Comparative Example 88

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 81.

TABLE 81 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 88 BH-5 BD-10 114 0.133 0.078 ComparativeExample 88 BH-5-a BD-10 80 0.133 0.078

Example 89 and Comparative Example 89

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 82.

TABLE 82 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 89 BH-6 BD-10 220 0.133 0.078 ComparativeExample 89 BH-6-a BD-10 142 0.133 0.078

Example 90 and Comparative Example 90

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 83.

TABLE 83 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 90 BH-7 BD-10 187 0.133 0.078 ComparativeExample 90 BH-7-a BD-10 124 0.133 0.078

Example 91 and Comparative Example 91

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 84.

TABLE 84 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 91 BH-8 BD-10 189 0.133 0.079 ComparativeExample 91 BH-8-a BD-10 126 0.133 0.079

Example 92 and Comparative Example 92

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 85.

TABLE 85 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 92 BH-9 BD-10 161 0.133 0.079 ComparativeExample 92 BH-9-a BD-10 131 0.133 0.079

Example 93 and Comparative Example 93

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 86.

TABLE 86 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 93 BH-10 BD-10 166 0.133 0.079 ComparativeExample 93 BH-10-a BD-10 110 0.133 0.079

Example 94 and Comparative Example 94

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 87.

TABLE 87 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 94 BH-11 BD-10 201 0.133 0.079 ComparativeExample 94 BH-11-a BD-10 131 0.133 0.079

Example 95 and Comparative Example 95

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 88.

TABLE 88 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 95 BH-12 BD-10 198 0.133 0.078 ComparativeExample 95 BH-12-a BD-10 143 0.133 0.078

Example 96 and Comparative Example 96

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 89.

TABLE 89 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 96 BH-13 BD-10 99 0.133 0.078 ComparativeExample 96 BH-13-a BD-10 67 0.133 0.078

Example 97 and Comparative Example 97

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 90.

TABLE 90 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 97 BH-15 BD-10 116 0.133 0.078 ComparativeExample 97 BH-15-a BD-10 82 0.133 0.078

Example 98

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 91.

TABLE 91 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 98 BH-16 BD-10 165 0.133 0.078

Example 99 and Comparative Example 99

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 92.

TABLE 92 Emitting layer Hosting Dopant Chromaticity material materialLT95(h) CIEx CIEy Example 99 BH-17 BD-10 224 0.133 0.078 ComparativeExample 99 BH-17-a BD-10 144 0.133 0.078

Example 100 and Comparative Example 100

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 93.

TABLE 93 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 100 BH-1 BD-11 163 0.133 0.076 ComparativeBH-1-a BD-11 115 0.133 0.076 Example 100

Example 101 and Comparative Example 101

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 94.

TABLE 94 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 101 BH-2 BD-11 95 0.133 0.076 ComparativeBH-2-a BD-11 77 0.133 0.076 Example 101

Example 102 and Comparative Example 102

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 95.

TABLE 95 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 102 BH-3 BD-11 179 0.133 0.076 ComparativeBH-3-a BD-11 135 0.133 0.076 Example 102

Example 103 and Comparative Example 103

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 96.

TABLE 96 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 103 BH-5 BD-11 101 0.133 0.076 ComparativeBH-5-a BD-11 77 0.133 0.076 Example 103

Example 104 and Comparative Example 104

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 97.

TABLE 97 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 104 BH-6 BD-11 175 0.133 0.076 ComparativeBH-6-a BD-11 133 0.133 0.076 Example 104

Example 105 and Comparative Example 105

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 98.

TABLE 98 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 105 BH-7 BD-11 169 0.133 0.076 ComparativeBH-7-a BD-11 117 0.133 0.076 Example 105

Example 106 and Comparative Example 106

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 99.

TABLE 99 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 106 BH-8 BD-11 168 0.133 0.077 ComparativeBH-8-a BD-11 125 0.133 0.077 Example 106

Example 107 and Comparative Example 107

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 100.

TABLE 100 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 107 BH-9 BD-11 197 0.133 0.077 ComparativeBH-9-a BD-11 127 0.133 0.077 Example 107

Example 108 and Comparative Example 108

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 101.

TABLE 101 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 108 BH-10 BD-11 154 0.133 0.077 ComparativeBH-10-a BD-11 105 0.133 0.077 Example 108

Example 109 and Comparative Example 109

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 102.

TABLE 102 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 109 BH-11 BD-11 188 0.133 0.077 ComparativeBH-11-a BD-11 127 0.133 0.077 Example 109

Example 110 and Comparative Example 110

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 103.

TABLE 103 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 110 BH-12 BD-11 181 0.133 0.076 ComparativeBH-12-a BD-11 125 0.133 0.076 Example 110

Example 111 and Comparative Example 111

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 104.

TABLE 104 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 111 BH-13 BD-11 94 0.133 0.076 ComparativeBH-13-a BD-11 62 0.133 0.076 Example 111

Example 112 and Comparative Example 112

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 105.

TABLE 105 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 112 BH-15 BD-11 101 0.133 0.076 ComparativeBH-15-a BD-11 68 0.133 0.076 Example 112

Example 113

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 106.

TABLE 106 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 113 BH-16 BD-11 157 0.133 0.076

Example 114 and Comparative Example 114

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 107.

TABLE 107 Emitting layer Hosting Dopant Chromaticity material materialLT95 (h) CIEx CIEy Example 114 BH-17 BD-11 211 0.133 0.076 ComparativeBH-17-a BD-11 135 0.133 0.076 Example 114

Example 115 and Comparative Example 115

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 108.

TABLE 108 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 115 BH-1 BD-12 112 0.141 0.058 ComparativeBH-1-a BD-12  85 0.141 0.058 Example 115

Example 116 and Comparative Example 116

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 109.

TABLE 109 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 116 BH-2 BD-12 88 0.141 0.058 ComparativeBH-2-a BD-12 58 0.141 0.058 Example 116

Example 117 and Comparative Example 117

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 110.

TABLE 110 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 117 BH-3 BD-12 143 0.141 0.058 ComparativeBH-3-a BD-12 100 0.141 0.058 Example 117

Example 118 and Comparative Example 118

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 111.

TABLE 111 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 118 BH-5 BD-12 80 0.141 0.058 ComparativeBH-5-a BD-12 59 0.141 0.058 Example 118

Example 119 and Comparative Example 119

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 112.

TABLE 112 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 119 BH-6 BD-12 151 0.141 0.058 ComparativeBH-6-a BD-12 100 0.141 0.058 Example 119

Example 120 and Comparative Example 120

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 113.

TABLE 113 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 120 BH-7 BD-12 138 0.141 0.058 ComparativeBH-7-a BD-12  90 0.141 0.058 Example 120

Example 121 and Comparative Example 121

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 114.

TABLE 114 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 121 BH-8 BD-12 137 0.141 0.059 ComparativeBH-8-a BD-12  90 0.141 0.059 Example 121

Example 122 and Comparative Example 122

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 115.

TABLE 115 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 122 BH-9 BD-12 125 0.141 0.059 ComparativeBH-9-a BD-12  91 0.141 0.059 Example 122

Example 123 and Comparative Example 123

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 116.

TABLE 116 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 123 BH-10 BD-12 116 0.141 0.059 ComparativeBH-10-a BD-12  80 0.141 0.059 Example 123

Example 124 and Comparative Example 124

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 117.

TABLE 117 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 124 BH-11 BD-12 128 0.141 0.059 ComparativeBH-11-a BD-12  94 0.141 0.059 Example 124

Example 125 and Comparative Example 125

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 118.

TABLE 118 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 125 BH-12 BD-12 125 0.141 0.058 ComparativeBH-12-a BD-12  90 0.141 0.058 Example 125

Example 126 and Comparative Example 126

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 119.

TABLE 119 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 126 BH-13 BD-12 73 0.141 0.058 ComparativeBH-13-a BD-12 50 0.141 0.058 Example 126

Example 127 and Comparative Example 127

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 120.

TABLE 120 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 127 BH-15 BD-12 82 0.141 0.058 ComparativeBH-15-a BD-12 52 0.141 0.058 Example 127

Example 128

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 121.

TABLE 121 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 128 BH-16 BD-12 122 0.141 0.058

Example 129 and Comparative Example 129

The organic EL device was fabricated in the same manner as in Example 1except that the compound indicated in the following table was used asmaterials for the emitting layer (host material and dopant material),and evaluated. The results are shown in Table 122.

TABLE 122 Emitting layer Chromaticity Hosting material Dopant materialLT95(h) CIEx CIEy Example 129 BH-17 BD-12 155 0.141 0.058 ComparativeBH-17-a BD-12 105 0.141 0.058 Example 129

From the results shown in Tables 1 to 122, when the compound (hostmaterial) represented by the formula (1) (for example the compoundrepresented by the formula (1A)) which has a deuterium atom at aparticular position is used for the emitting layer in combination of aparticular dopant material, it is understood that the lifetime of theorganic EL device becomes longer than that of one which uses a compound(host material) which has no deuterium atom at the particular positionin combination with the corresponding dopant material.

Several embodiments and/or examples of the present invention have beendescribed in detail above. However, without substantially departing fromnovel teachings and effects of the present invention, the person skilledin the art can readily make a number of modifications to the embodimentsand/or examples which are exemplifications of these teachings andeffects. Thus, these modifications are included in the scope of thepresent invention.

The documents described in this specification and the contents of theapplication that serves as the basis of priority claim under Parisconvention are incorporated herein by reference in its entirety.

1. An organic electroluminescence device comprising: a cathode, ananode, and an emitting layer disposed between the cathode and the anode,wherein the emitting layer comprises a compound represented by thefollowing formula (1A) and a compound represented by the followingformula (43D):

wherein in the formula (1A), R_(1A) to R_(8A) are independently ahydrogen atom, and at least one of R_(1A) to R_(8A) is a deuterium atom;L_(1A) and L_(2A) are independently a single bond, an unsubstitutedphenylene group, or an unsubstituted naphthylene group; Ar_(1A) is asubstituted or unsubstituted phenyl group or a substituted orunsubstituted naphthyl group, and the substituent for Ar_(1A) is aphenyl group; Ar_(2A) is a monovalent group represented by the followingformula (2A), (3A) or (4A):

wherein in the formulas (2A) to (4A), any one of R_(13A) to R_(14A) is asingle bond that binds to L_(2A); and R_(11A), R_(12A), R_(15A) toR_(20A), as well as R_(13A) to R_(14A) that are not a single bondbonding to L_(2A) are independently a hydrogen atom or an unsubstitutedaryl group including 6 to 50 ring carbon atoms;

wherein in the formula (43D), R₄₆₁₁ is a hydrogen atom, an unsubstitutedalkyl group including 1 to 6 carbon atoms, an unsubstituted cycloalkylgroup including 3 to 10 ring carbon atoms, —Si(R₉₁₁)(R₉₁₂)(R₉₁₃), or—N(R₉₁₄)(R₉₁₅); R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkylgroup including 1 to 6 carbon atoms, an unsubstituted cycloalkyl groupincluding 3 to 10 ring carbon atoms, or —Si(R₉₁₁)(R₉₁₂)(R₉₁₃); R₉₁₁ to8913 are independently an unsubstituted alkyl group including 1 to 6carbon atoms or an unsubstituted aryl group including 6 to 18 ringcarbon atoms; and R₉₁₄ to R₉₁₅ are independently an unsubstituted arylgroup including 6 to 18 ring carbon atoms.
 2. The organicelectroluminescence device according to claim 1, wherein in the formula(1A), at least two of R_(1A) to R_(8A) are deuterium atoms.
 3. Theorganic electroluminescence device according to claim 1, wherein in theformula (1A), R_(1A) to R_(8A) are all deuterium atoms.
 4. The organicelectroluminescence device according to claim 1, wherein in the formula(1A), at least one hydrogen atom contained in Ar_(1A) is a deuteriumatom.
 5. The organic electroluminescence device according to claim 1,wherein in the formula (1A), R_(11A), R_(12A), R_(15A) to R_(20A), aswell as R_(13A) to R_(14A) that are not a single bond bonding to L_(2A)are hydrogen atoms.
 6. The organic electroluminescence device accordingto claim 1, wherein in the formula (1A), at least one of R_(11A),R_(12A), R_(15A) to R_(20A), as well as R_(13A) to R_(14A) that are nota single bond bonding to L_(2A) is a deuterium atoms.
 7. The organicelectroluminescence device according to claim 1, wherein in the emittinglayer, based on the total of the compound represented by the formula(1A) and the compound having the same structure as the compoundrepresented by the formula (1A) except that the compound represented bythe formula (1A) contains only protium atoms as hydrogen atoms, thecontent ratio of the latter is 99 mol % or less.
 8. The organicelectroluminescence device according to claim 1, wherein in the formula(43D), R₄₆₁₁ is a hydrogen atom, an unsubstituted alkyl group including1 to 6 carbon atoms, or —N(R₉₁₄)(R₉₁₅).
 9. The organicelectroluminescence device according to claim 1, wherein in the formula(43D), R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl groupincluding 1 to 6 carbon atoms, or an unsubstituted cycloalkyl groupincluding 3 to 10 ring carbon atoms.
 10. The organic electroluminescencedevice according to claim 1, wherein in the formula (430), R₄₆₁₁ is—N(R₉₁₄)(R₉₁₅), and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstitutedalkyl group including 1 to 6 carbon atoms.
 11. The organicelectroluminescence device according to claim 1, wherein in the formula(43D), R₄₆₁₁ is an unsubstituted alkyl group including 1 to 6 carbonatoms, and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstituted alkyl groupincluding 1 to 6 carbon atoms.
 12. The organic electroiuminescencedevice according to claim 1, wherein in the formula (43D), R₄₆₁₁ is ahydrogen atom, and R₄₆₁₂ to R₄₆₁₅ are independently an unsubstitutedalkyl group including 1 to 6 carbon atoms, or an unsubstitutedcycloalkyl group including 3 to 10 ring carbon atoms.
 13. The organicelectroluminescence device according to claim 1, wherein in the formula(43D), at least one of the hydrogen atoms included in one or moreselected from the group consisting of R₉₁₄ and R₉₁₅ is a deuterium atom.14. The organic electroluminescence device according to claim 1, whereinthe compound represented by the formula (1A) is one or more selectedfrom the group consisting of the compound represented by the formulasBH-1 to BH-3, BH-5 to BH-13 and BH-15 to BH-17, and the compoundrepresented by the formula (43D) is one or more selected from the groupconsisting of the compound represented by the formulas BD-9, BD-10,BD-11 and BD-12.


15. The organic electroluminescence device according to claim 1, whichfurther comprises a hole-transporting layer between the anode and theemitting layer.
 16. The organic electroluminescence device according toclaim 1, which further comprises an electron-transporting layer betweenthe cathode and the emitting layer.
 17. An electronic apparatus whereinthe organic electroluminescence device according to claim 1 is provided.